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`EXHIBIT E
`EXHIBIT E
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`Case 2:20-cv-00048-JRG Document 1-5 Filed 02/21/20 Page 2 of 10 PageID #: 160
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`(12) United States Patent
`Easter et al.
`
`USOO6596639B1
`(10) Patent No.:
`US 6,596,639 B1
`(45) Date of Patent:
`Jul. 22, 2003
`
`(54) METHOD FOR CHEMICAL/MECHANICAL
`PLANARIZATION OF A SEMCONDUCTOR
`WAFER HAVING DSSIMILAR METAL
`PATTERN DENSITES
`
`(75) Inventors: William G. Easter, Orlando, FL (US);
`Sudhanshu Misra, Orlando, FL (US);
`Vivek Saxena, Orlando, FL (US)
`(73) ASSignee: his Systems Inc., Allentown, PA
`-
`Subject to any disclaimer, the term of this
`patent is extended or adjusted under 35
`U.S.C. 154(b) by 0 days.
`
`(*) Notice:
`
`(21) Appl. No.: 09/415,529
`(22) Filed:
`Oct. 8, 1999
`(51) Int. Cl. .............................................. H01L 21/302
`(52) U.S. Cl. ....................... 438/692; 438/626; 438/633;
`438/699
`(58) Field of Search ......................... 438,626,631-634,
`438/645, 692
`
`(56)
`
`References Cited
`
`U.S. PATENT DOCUMENTS
`5,516,729 A * 5/1996 Dawson et al. ............. 438/623
`5,866,945 A * 2/1999 Chen et al. ................. 257/750
`
`5,893,750 A * 4/1999 Hause et al................. 438/633
`
`JP
`
`FOREIGN PATENT DOCUMENTS
`10-135209
`* 5/1998
`
`* cited by examiner
`Primary Examiner Wael Fahmy
`Assistant Examiner Marcos D. Pizarro-Crespo
`(57)
`ABSTRACT
`The present invention provides a method of manufacturing
`an integrated circuit including planarizing a Semiconductor
`wafer Surface. In one embodiment, the method comprises
`forming a dielectric layer over a first level having an
`irregular topography, depositing a Sacrificial material Over
`the dielectric layer, and then planarizing the Semiconductor
`wafer Surface to a planar Surface. More Specifically, the
`dielectric layer forms Such that it Substantially conforms to
`the irregular topography of the first level. The Sacrificial
`material is formed to a Substantially planar Surface Over the
`dielectric layer. Thus, the Sacrificial material provides a
`Substantially uniform chemical/mechanical planarization
`(CMP) process removal rate across the semiconductor wafer
`Surface. In the ensuing Step, planarizing the Semiconductor
`wafer Surface to a planar Surface removes the Sacrificial
`material and a portion of the dielectric layer with a CMP
`proceSS.
`
`14 Claims, 4 Drawing Sheets
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`Case 2:20-cv-00048-JRG Document 1-5 Filed 02/21/20 Page 3 of 10 PageID #: 161
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`U.S. Patent
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`Jul. 22, 2003
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`US 6,596,639 B1
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`Case 2:20-cv-00048-JRG Document 1-5 Filed 02/21/20 Page 4 of 10 PageID #: 162
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`Jul. 22, 2003
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`Case 2:20-cv-00048-JRG Document 1-5 Filed 02/21/20 Page 5 of 10 PageID #: 163
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`Case 2:20-cv-00048-JRG Document 1-5 Filed 02/21/20 Page 6 of 10 PageID #: 164
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`Case 2:20-cv-00048-JRG Document 1-5 Filed 02/21/20 Page 7 of 10 PageID #: 165
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`US 6,596,639 B1
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`1
`METHOD FOR CHEMICAL/MECHANICAL
`PLANARIZATION OF A SEMCONDUCTOR
`WAFER HAVING DSSIMILAR METAL
`PATTERN DENSITIES
`
`TECHNICAL FIELD OF THE INVENTION
`The present invention is directed, in general, to Semicon
`ductor manufacturing and, more specifically, to a method
`involving applying a Sacrificial material to a Substantially
`planar condition prior to planarizing a Semiconductor wafer
`having an interlayer dielectric over dissimilar metal pattern
`density areas.
`BACKGROUND OF THE INVENTION
`Dielectric and metal layers used in chip fabrication today
`must be made extremely flat and of precise thickness in
`order to photolithographically pattern the Sub-micron sized
`features that comprise a Semiconductor device. During
`chemical/mechanical planarization (CMP), the combination
`of chemical etching and mechanical abrasion produces the
`required flat, precise Surface for Subsequent depositions.
`Commonly, the functional complexity of the circuits with
`Shrinking dimensions is limited by the characteristics of the
`metallic conductors (commonly referred to as interconnects)
`that provide the electrical connections between the circuit
`elements. Key characteristics considered when employing
`Such interconnects are the minimum width and Separation of
`the conductor features as well as the total number of
`interconnect levels that are required. The non-planarity of
`the top Surface of an integrated circuit is determined by the
`cumulative non-planarity of all the underlying levels.
`Therefore, as the number of underlying interconnect levels
`is increased, the planarization precision at each level
`becomes more important as errors are cumulative to the
`uppermost level. For a more thorough discussion of pla
`narization and the effects of non-planarity on
`photolithography, see S. Wolf's, Silicon Processing for the
`VLSI Era, Vol. 2, which is incorporated herein by reference.
`CMP preferentially removes the high portions of what
`ever layer is being planarized. In many instances, the layer
`is an interlayer dielectric (ILD) that occurs in areas directly
`above underlying interconnect topography. During
`deposition, the ILD follows the general contours of the
`previous layer, Such that relatively complex interconnect
`areas have resultant large contiguous dielectric deposition
`thereon. That is, during deposition the dielectric "mush
`rooms' around each feature as the feature acts like a stem of
`a mushroom. Referring initially to FIGS. 1A-1B, illustrated
`are Sectional views of a conventional planarization process.
`FIG. 1A illustrates a sectional view of three different areas
`of interconnect pattern density 110, 120, 130 with a dielec
`tric layer 140 deposited thereon. Pattern density is defined,
`for this discussion, as the normalized percentage of the total
`Surface area of a Substrate that is covered with interconnects.
`For example, pattern density may be expressed as the
`percentage of metal interconnect area per Surface area. Thus,
`closely spaced interconnects will have a higher pattern
`density. With a single interconnect 111, the dielectric 140
`forms a mushroom 112 about the single interconnect 111 that
`is essentially equal on each side 111a, 111b of the intercon
`nect 111. When dual interconnects 121, 122 are sufficiently
`close, a mushroom 123 extends to either side of the outer
`most interconnect sides 126, 127. In the case of a plurality
`of conventional interconnect structures (designated as
`131a–131n), the dielectric layer 140 forms such that the
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`surface 133 over the interconnects 131a–131n is essentially
`planar, while the mushroom 134 forms beyond outer edges
`136 and 137 of the outermost interconnects 131a, 131n. As
`can be seen, between areas 110, 120, and 130, valleys 150
`occur in the dielectric 140 where interconnects do not exist.
`FIG. 1B illustrates the results of a CMP process per
`formed on the interconnect densities of FIG. 1A. During the
`CMP process, the dielectric removal rate is slower for
`regions with a high density 130 of underlying interconnect
`Structures because a large fraction of the wafer Surface
`contacts the polishing pad in these regions. One who is
`skilled in the art is familiar with conventional CMP pro
`cesses. Conversely, areas of low pattern interconnect density
`110, 120 encounter significantly faster removal of material
`during CMP. Consequently, the height of the dielectric layer
`140 may vary dramatically across the chip depending on the
`underlying metal pattern density. While the surface 141 of
`the dielectric layer 140 is locally planar, the pattern density
`variation in the underlying interconnect structures 110, 120,
`130 creates an unacceptable amount of non-planarity in the
`dielectric surface 141 as indicated by the variation in the
`dielectric layer thicknesses 115, 125, 135 in different areas
`of the die. Following the CMP process, thicknesses 115,125,
`135 will vary, such that: thickness 115 is less than thickness
`125, is less than thickness 135. Therefore, the desired
`planarity is jeopardized.
`One approach that has been taken to compensate for this
`problem is termed metal topography reduction (MTR),
`which is discussed in U.S. patent application Ser. No.
`09/298,792 filed on Apr. 23, 1999 entitled “Method of
`Planarizing a Surface of an Integrated Circuit” which is
`incorporated herein by reference. This involves forming a
`photoresist material over selected recessed areas of a die
`such as the valleys 150 of FIG. 1A, etching the photoresist,
`and then partially etching into protruding areas 112, 123,
`133 to roughly level the die surface. The semiconductor die
`are then conventionally planarized. Of course, this intro
`duces an additional photolithographic Step and a plasma etch
`of the dielectric to reduce the area of the dielectric in those
`areas with a high area density of metal. This Somewhat
`reduces the effects of the higher and lower pattern densities.
`While Some Success has been achieved with metal topogra
`phy reduction, the additional photolithographic and etching
`StepS are both expensive and time consuming.
`Accordingly, what is needed in the art is an inexpensive
`method of preparing a Semiconductor wafer for chemical/
`mechanical planarization of the interlayer dielectric.
`SUMMARY OF THE INVENTION
`To address the above-discussed deficiencies of the prior
`art, the present invention provides a method of manufactur
`ing an integrated circuit including planarizing an irregular
`Semiconductor wafer Surface. In one embodiment, the
`method comprises forming an interlayer dielectric over a
`first level having an irregular topography, depositing a
`Sacrificial material over the dielectric layer, and then pla
`narizing the Semiconductor wafer Surface to a planar Surface.
`More specifically, the dielectric layer forms such that it
`Substantially conforms to the irregular topography of the
`first level. The sacrificial material is formed to a Substan
`tially planar Surface over the dielectric layer. Thus, the
`Sacrificial material provides a Substantially uniform
`chemical/mechanical planarization (CMP) process removal
`rate acroSS the Semiconductor wafer Surface. In the ensuing
`Step, planarizing the Semiconductor wafer Surface to a planar
`Surface removes the Sacrificial material and a portion-of the
`dielectric layer with the CMP process.
`
`
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`US 6,596,639 B1
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`3
`Thus, in a-broad aspect, a Sacrificial material is deposited
`upon an interlayer dielectric that has conformed to an
`underlying, irregular topography. The Sacrificial material
`forms a Substantially planar Surface over the irregular
`topography, and it has a CMP process removal rate Substan
`tially equal to the removal rate of the dielectric layer. For this
`discussion, a Substantially planar Surface is a Surface where
`the difference between the highest and lowest points is no
`greater than about 15 percent to 20 percent of the thickneSS
`as measured from a datum plane. Therefore, in the imme
`diately ensuing Step of planarizing, the dielectric layer and
`Sacrificial material are removed at Substantially the same
`rate, resulting in a planar Surface. A planar Surface, for this
`discussion, is a Surface where the difference between the
`highest and lowest points is less than about 10 percent of the
`thickneSS as measured from the same datum plane, rather
`than absolutely planar.
`In an alternative embodiment, the method includes form
`ing a dielectric layer that Substantially conforms to an
`irregular topography comprising a lower pattern density
`region and a higher pattern density region. In this instance,
`the dielectric layer has a higher CMP process removal rate
`over the lower pattern density region than over the higher
`pattern density region. Planarizing, in another embodiment,
`includes removing essentially all of the Sacrificial material
`and at least a portion of the dielectric layer.
`In another embodiment, the method includes depositing a
`spin-on material. In a further aspect, the method includes
`depositing a spin-on material having a Selectivity Substan
`tially equal to a Selectivity of the dielectric layer.
`Specifically, the Sacrificial material may be: methylsiloxane,
`fluorinated Silicon glass, or phosphosilicate glass.
`Alternatively, the Sacrificial material may be inorganic spin
`on polymer Such as polyperhydrido Siloxane or hydrogen
`Silsesquioxane (HSiO2). In yet another embodiment, the
`method includes forming an interlayer dielectric having a
`Selectivity greater or less than about 1:1 and varying a
`thickness of the spin-on material to compensate for the
`Selectivity being greater or less than about 1:1. Selectivity,
`for the purposes of this discussion, is the ratio of the removal
`rate of one material to that of another Standard material
`under the same conditions. In a particularly advantageous
`embodiment, the method includes forming an interlayer
`dielectric having a Selectivity of about 1:1 to the Sacrificial
`layer.
`The foregoing has outlined, rather broadly, preferred and
`alternative features of the present invention So that those
`skilled in the art may better understand the detailed descrip
`tion of the invention that follows. Additional features of the
`invention will be described hereinafter that form the subject
`of the claims of the invention. Those skilled in the art should
`appreciate that they can readily use the disclosed conception
`and Specific embodiment as a basis for designing or modi
`fying other Structures for carrying out the same purposes of
`the present invention. Those skilled in the art should also
`realize that Such equivalent constructions do not depart from
`the Spirit and Scope of the invention in its broadest form.
`BRIEF DESCRIPTION OF THE DRAWINGS
`For a more complete understanding of the present
`invention, reference is now made to the following descrip
`tions taken in conjunction with the accompanying drawings,
`in which:
`FIG. 1A illustrates a sectional view of three different areas
`of interconnect pattern density with a dielectric layer depos
`ited thereon
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`FIG. 1B illustrates the results of a CMP process per
`formed on the interconnect densities of FIG. 1A;
`FIG. 2 illustrates a sectional view of a simplified semi
`conductor wafer having three different areas of interconnect
`pattern density with a conventional interlayer dielectric
`deposited thereon;
`FIG. 3 illustrates a sectional view of the semiconductor
`wafer of FIG.2 after deposition of a sacrificial material upon
`the interlayer dielectric,
`FIG. 4 illustrates a sectional view of the semiconductor
`wafer 200 of FIG. 3 as planarization begins;
`FIG. 5 illustrates a sectional view of the semiconductor
`wafer of FIG. 4 as planarization of the interlayer dielectric
`begins,
`FIG. 6 illustrates a sectional view of the semiconductor
`wafer of FIG. 5 after completing planarization; and
`FIG. 7 illustrates a partial sectional view of a conventional
`integrated circuit that can be manufactured using a method
`for planarizing a Semiconductor wafer Surface in accordance
`with the principles of the present invention.
`
`DETAILED DESCRIPTION
`Referring now to FIG. 2, illustrated is a sectional view of
`a simplified semiconductor wafer 200 having three different
`areas of interconnect pattern density 210, 220, 230 with a
`conventional interlayer dielectric 240 deposited thereon. For
`this discussion, pattern density is defined as the normalized
`percentage of the total Surface area of a Substrate that is
`covered with interconnects, that is: the percentage of metal
`interconnect area per Surface area. The area may be
`expressed in any units Suitable for the Semiconductor in
`question, i.e., mm, etc. Thus, closely spaced interconnects
`will have a higher pattern density. The Sectional view is
`termed “simplified” because lower levels of semiconductor
`Structure, Such as gates, Sources, drains, etc., have been
`omitted for clarity as they do not affect the present discus
`SO.
`The first pattern density area 210, exemplifying a very
`low pattern density, has a single interconnect 211 around
`which the interlayer dielectric 240 forms a mushroom 212.
`The mushroom 212 forms essentially equally on sides 211a,
`2.11b of the interconnect 211. In the second pattern density
`area 220, dual interconnects 221, 222 are sufficiently close
`that a mushroom 223 extends to either side of the outermost
`interconnect sides 226, 227. The third pattern density area
`230, exemplifying a very high pattern density, comprises a
`plurality of conventional interconnect structures (designated
`as 231a–231n). In this instance, the dielectric layer 240
`forms an essentially planar surface 233 over the interior
`interconnects 231b-231 m. The mushroom 234 forms
`beyond outer edges 236 and 237 of the outermost intercon
`nects 231a, 231n. Valleys 250 occur in the interlayer dielec
`tric 240 between areas 210, 220, and 230 where intercon
`nects do not exist. Each material used for an interlayer
`dielectric 240 has a selectivity value associated therewith.
`Selectivity is defined, for this discussion, as the polish rate
`of one material divided by the polish rate of a comparison
`material under the same conditions and as Such is dimen
`Sionless.
`Referring now to FIG. 3, illustrated is a sectional view of
`the semiconductor wafer 200 of FIG. 2 after deposition of a
`sacrificial material 310 upon the interlayer dielectric 240.
`The sacrificial material 310 may be applied by spin-on
`techniques employing a material that has a Selectivity Sub
`Stantially equal to the Selectivity of the interlayer dielectric
`
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`240. In one advantageous embodiment, the selectivity of the
`sacrificial material 310 is about 1:1. Specific materials that
`may be used in the Spin-on deposition include:
`methylsiloxane, fluorinated Silicon glass, or phosphosilicate
`glass. Alternatively, an inorganic spin-on polymer Such as
`polyperhydrido Siloxane or hydrogen-silsesquioxane
`(HSiO2), may also be used as the Sacrificial spin-on
`material. Of course, other spin-on materials may also be
`used if they have acceptable Selectivities. The Sacrificial
`spin-on material 310 is deposited until a Substantially planar
`surface 350 results. A substantially planar surface 350, for
`this intermediate State, is defined as one in which any height
`355 of the substantially planar Surface 350 above a datum
`plane 357, e.g., a back 360 of the semiconductor wafer 200,
`varies by no more than about 15 percent to 20 percent of a
`maximum height 359 of the substantially planar surface 350.
`The next process for the semiconductor wafer 200 after
`spin-on deposition is planarization without intervening
`Steps, e.g., etching, masking, etc. Referring now to FIG. 4,
`illustrated is a Sectional view of the Semiconductor wafer
`200 of FIG. 3 as planarization begins. In the illustrated
`embodiment, planarization begins with a polishing pad 410
`conforming to the substantially planar surface 350 of the
`Sacrificial material 310. Planarization proceeds, and a major
`portion of the sacrificial material 310 is removed. During
`this phase, the Selectivity in effect is that of the Sacrificial
`material 310, and high spots 459 are removed. Because the
`variation between a maximum height 359 and a minimum
`height 469 is no more than about 15 percent to 20 percent of
`the maximum height 359, during polishing the maximum
`height 359 is slowly reduced to approximately the minimum
`height 469. Thus, minor high spots 459 on the sacrificial
`material 310 have been reduced prior to the polishing pad
`410 contacting the interlayer dielectric 240.
`In an alternative embodiment when the selectivity of the
`interlayer dielectric 240 cannot be exactly matched, the
`thickness of the sacrificial material 310 may be adjusted to
`compensate for a greater or less than 1:1 Selectivity between
`the interlayer dielectric 240 and the spin-on material 310.
`Referring now to FIG. 5, illustrated is a sectional view of
`the semiconductor wafer 200 of FIG. 4 as planarization of
`the interlayer dielectric 240 begins. It is important to note
`that, at this time, the selectivity of the sacrificial material 310
`and the selectivity of the interlayer dielectric 240 are sub
`stantially equal. Therefore, the CMP process affects both the
`sacrificial material 310 and the interlayer dielectric 240
`approximately uniformly across the wafer 200. That is,
`material removal of the sacrificial material 310 and the
`interlayer dielectric 240 is substantially uniform. Therefore,
`material removal in regions 530 over high pattern density
`areas 230 are removed at the same rate as regions 510, 520
`over low pattern density areas 210, 220.
`Referring now to FIG. 6 with continuing reference to FIG.
`5, illustrated is a sectional view of the semiconductor wafer
`200 of FIG. 5 after completing planarization. Because the
`removal rate for the sacrificial material 310 and the inter
`layer dielectric 240 was Substantially equal, it was possible
`to planarize the intermediate layer dielectric 240. Planarized,
`for this discussion, is the condition Such that for any point
`on a Surface 610 of the wafer 200, there is a variation of no
`more than about 10 percent of the maximum height between
`the lowest point on the wafer 200 and the highest point on
`the wafer 200.
`Referring now to FIG. 7, illustrated is a partial sectional
`view of a conventional integrated circuit 700 that can be
`manufactured using a method for planarizing a Semiconduc
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`tor wafer Surface in accordance with the principles of the
`present invention. In this particular Sectional view, there is
`illustrated an active device 710 that comprises a tub region
`720, Source/drain regions 730 and field oxides 740, which
`together may form a conventional transistor, Such as a
`CMOS, PMOS, NMOS or bi-polar transistor. A contact plug
`750 contacts the active device 710. The contact plug 750 is,
`in turn, contacted by a trace 760 that connects to other
`regions of the integrated circuit, which are not shown. AVIA
`770 contacts the trace 760, which provides electrical con
`nection to Subsequent levels of the integrated circuit.
`Thus, a method for planarizing a Semiconductor wafer
`Surface having an irregular interlayer dielectric topography
`has been described. The method involves depositing a
`spin-on layer of a Sacrificial material having a Selectivity
`Substantially equal to the Selectivity of the interlayer dielec
`tric. The spin-on layer is deposited to a Substantially planar
`State, and planarization begins directly following that depo
`Sition. Photomasks, etching, etc. are thereby avoided. Pla
`narization proceeds until all of the Sacrificial material has
`been removed and a portion of the dielectric layer. The result
`is a planarized Surface that has no more than a 10 percent
`variation of wafer thickness acroSS the wafer.
`Although the present invention has been described in
`detail, those skilled in the art should understand that they can
`make various changes, Substitutions and alterations herein
`without departing from the Spirit and Scope of the invention
`in its broadest form.
`What is claimed is:
`1. A method for planarizing a Semiconductor wafer
`Surface, comprising:
`forming a dielectric layer over a first level having an
`irregular topography, Said dielectric layer Substantially
`conforming to Said irregular topography;
`depositing a Sacrificial material over Said dielectric layer,
`Said Sacrificial material forming a Substantially planar
`Surface and having a chemical/mechanical planariza
`tion (CMP) process removal rate substantially equal to
`a CMP process removal rate of said dielectric layer,
`wherein said CMP process removal rates of said sac
`rificial material and Said dielectric layer provide a
`Substantially uniform CMP process removal rate across
`a Semiconductor wafer Surface; and then
`planarizing Said Semiconductor wafer Surface to a planar
`Surface by removing Said Sacrificial material and a
`portion of said dielectric layer with a CMP process.
`2. The method as recited in claim 1 wherein forming
`includes forming a dielectric layer over a first level having
`an irregular topography, Said irregular topography compris
`ing a lower pattern density region and a higher pattern
`density region, Said dielectric layer having a higher CMP
`process removal rate over Said lower pattern density region
`than over Said higher pattern density region.
`3. The method as recited in claim 1 wherein planarizing
`includes removing essentially all of Said Sacrificial material
`and at least a portion of Said dielectric layer.
`4. The method as recited in claim 1 further comprising
`varying a thickness of Said Sacrificial material to compensate
`for a difference between said CMP process removal rate of
`said sacrificial material and said CMP process removal rate
`of Said dielectric layer.
`5. The method as recited in claim 1 wherein depositing
`includes depositing a spin-on material.
`6. The method as recited in claim 5 wherein depositing
`includes depositing a sacrificial material Selected from the
`group consisting of
`
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`7
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`methyl Siloxane,
`fluorinated Silicon glass, and
`phosphosilicate glass.
`7. The method as recited in claim 5 wherein depositing
`includes depositing an inorganic spin-on polymer Selected
`from the group consisting of:
`polyperhydrido Siloxane, and
`hydrogen-silsesquioxane (HSiO2),
`8. A method for manufacturing an integrated circuit,
`compriSIng:
`forming active devices on a Semiconductor wafer Surface;
`forming a first level interconnecting Said active devices
`and having an irregular topography over Said active
`devices,
`forming an interlayer dielectric over Said first level, Said
`interlayer dielectric Substantially conforming to Said
`irregular topography;
`depositing a sacrificial material over Said dielectric layer,
`Said Sacrificial material forming a Substantially planar
`Surface and having a chemical/mechanical planariza
`tion (CMP) process removal rate substantially equal to
`a CMP process removal rate of said dielectric layer,
`wherein said CMP process removal rates of said sac
`rificial material and Said dielectric layer provide a
`Substantially uniform CMP process removal rate across
`a Semiconductor wafer Surface; and then
`planarizing Said Semiconductor wafer Surface to a planar
`Surface by removing Said Sacrificial material and a
`portion of said interlayer dielectric with a CMP pro
`CCSS.
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`US 6,596,639 B1
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`8
`9. The method as recited in claim 8 wherein forming an
`interlayer dielectric includes forming an interlayer
`dielectric, Said irregular topography comprising a lower
`pattern density region and a higher pattern density region,
`Said interlayer dielectric having a higher CMP process
`removal rate over Said lower pattern density region than over
`Said higher pattern density region.
`10. The method as recited in claim 8 wherein planarizing
`includes removing essentially all of Said Sacrificial material
`and at least a portion of Said interlayer dielectric.
`11. The method as recited in claim 8 further comprising
`varying a thickness of Said Sacrificial material to compensate
`for a difference between said CMP process removal rate of
`said sacrificial material and said CMP process removal rate
`of Said dielectric layer.
`12. The method as recited in claim 8 wherein depositing
`includes depositing a spin-on material.
`13. The method as recited in claim 12 wherein depositing
`includes depositing a sacrificial material Selected from the
`group consisting of
`methyl Siloxane,
`fluorinated Silicon glass, and
`phosphosilicate Silicon glass.
`14. The method as recited in claim 12 wherein depositing
`includes depositing an inorganic spin-on polymer Selected
`from the group consisting of:
`polyperhydrido Siloxane, and
`hydrogen-silsesquioxane (HSiO2),
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