`
`(12) United States Patent
`Smith
`
`(10) Patent N0.:
`(45) Date of Patent:
`
`US 8,969,841 B2
`Mar. 3, 2015
`
`(54) LIGHT SOURCE FOR GENERATING LIGHT
`FROM A LASER SUSTAINED PLASNIA IN A
`ABOVE—A'I'MOSPHERIC PRESSURE
`CHAMBER
`
`USPC .................................................... .. 250/504 R
`See application file for complete search history.
`_
`References Cited
`
`(56)
`
`'5
`‘
`5
`.. 3
`‘S
`1
`(71) Applicant‘ Enerlretiq Technologv Inc Woburn.
`M/“U5?
`Inventor: Donald K. Smith, Boston, MA (US)
`
`(72)
`
`(73) Assignee: Encrgetiq Technology, Inc..Woburn.
`I
`‘
`
`( "‘ ) Notice:
`
`Subject to any disclaimer, the term of this
`patent is extended or adjusted under 35
`U_3_C_ 154(1)) by 0 days_
`
`.
`(21) Appl. No.. 14/510,959
`
`(22)
`
`Filed:
`
`Oct. 9. 2014
`
`{65 )
`
`Prior Publication Data
`US 2015i'002l500 Al
`Jan. 22. 2015
`
`Related U.S. Application Data
`
`(63) Continuation of application No. 13/964,938. filed on
`Aug. 12, 2013, which is a continuation of application
`No.
`l3r’O2-4.027. filed on Feb. 9, 2011, now Pat. No.
`8.525.138. which is
`a
`continuation-in-part of
`
`(Continued)
`
`(51)
`
`(2006-01‘)
`(200601 -’
`
`Int‘ Cl‘
`G011 3:/10
`G21K 3/04
`(52) U.S. C1.
`CFC -------------------------------------- -- G-21K 5/04 (201301)
`USPC ---------------------------------------------------- ~ 250/504 R
`(53) Field Of ClaSSifi¢3fi0I1 Search
`(‘PC ........... .. H01} 5/00: H01} 61/62; H01} 15/O0;
`HOlJ 15./'02‘. H050 2/00
`
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`Primary Examiner — Nicole lppolito
`Assistant Examiner —— Jason McC'.onnacl<
`
`(74) Allorizey. Agent, or Firm — Proskauer Rose LLP
`
`(57)
`ABSTRACT
`An apparatus for producing light includes a chamber and an
`ignition source that ionizes a gas within the chamber. The
`apparatus also includes at least one laser that provides energy
`to the ionized gas within the chamber to produce a high
`brightness light. The laser can provide a substantially con-
`tinuous amount of energy to the ionized gas to generate a
`substantially continuous high brightness light.
`
`30 Claims, 39 Drawing Sheets
`
`
`
`4!‘
`tot
`
`ASML 1101
`
`
`
`US 8,969,841 B2
`Page 2
`
`Related U.S. Application Data
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`application No. 12./166,918. filed on Jul. 2. 2008, now
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`
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`9, 2010.
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`US 8,969,84l B2
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`1
`LIGHT SOURCE FOR GENERATING LIGHT
`FROM A LASER SUSTAINED PLASMA IN A
`ABOVE-ATLVIOSPHERIC PRESSURE
`CHAMBER
`
`RELATED APPLICATIONS
`
`2
`Accordingly. a need therefore exists T01‘ an improved light
`source whose emitted light is not significantly affected when
`the light passes through a wall ofa chamber that includes the
`location from which the light is emitted.
`
`'1:
`
`SUMMARY OF THE INVENTION
`
`to
`
`‘Jr
`
`The present invention features a light source for generating
`a high brightness light.
`The invention. in one aspect, features a light source having
`a chamber. The light source also includes an ignition source
`for ionizing a gas within the chamber. The light source also
`includes at least one laser for providing energy to the ionized
`gas within the chamber to produce a high brightness light.
`In some embodiments. the at least one laser is a plurality of
`lasers directed at a region from which the high brightness
`light originates. In some embodiments, the light source also
`includes at least one optical element for modifying a property
`of the laser energy provided to the ionized
`The optical
`'_ “ element can be. for example. a lens (e.g._. an aplanatic lens. am
`achromatic lens. a single element lens. and a fresnel lens) or
`mirror (eg. a coated mirror. a dielectric coated mirror, a
`narrow band mirror. and an ultraviolet transparent infrared
`retlecting mirror). In some embodiments. the optical element
`is one or more fiber optic elements for directing the laser
`energy to the gas.
`The chamber can include an ultraviolet transparent region.
`The chamber or a window in the chamber can include a
`material selected from the group consisting of quartz, Supra-
`sili'f.C quartz (Heraeus Quartz America, LLC, Buford, Ga),
`sapphire. Mg}?1. diamond, and CaF2. ln some embodiments,
`the chamber is a sealed chamber. In some embodiments, the
`chamber is capable of being actively pumped. In some
`embodiments,
`the chamber includes a dielectric material
`(eg. quartz). The chamber can be. for example. a glass bulb.
`In some embodiments, the chamber is an ultraviolet transpar-
`ent dielectric chamber.
`The gas can be one or more ofa noble gas. Xe. Ar, Ne. Kr.
`He. D2. H2, 02, F2, 3 metal halide, a halogen, Hg, Cd, Zn. Sn,
`Ga. Fe, Li. Na, an excimer forming gas, air. a vapor. a metal
`oxide. an aerosol. a flowing media, or a recycled media. The
`gas can be produced by a pulsed laser beam that impacts a
`target (c.g.. a solid or liquid) in the chamber. The target can be
`a pool or film of metal. in some embodiments. the target is
`capable of moving. For example. the target may be a liquid
`that is directed to a region from which the high brightness
`ligit originates.
`In some embodiments. the at least one laser is multiple
`diode lasers coupled into a fiber optic element. In some
`‘ embodiments, the at least one laser includes a pulse or con-
`tinuous wave laser. In some embodiments, the at least one
`laser is an IR laser, a diode laser. a fiber laser, an ytterbium
`laser. a C03 laser, a YAG laser. or a gas discharge laser. In
`some embodiments. the at least one laser emits at least one
`wavelength of electromagnetic energy that
`is
`strongly
`absorbed by the ionized medium.
`The ignition source can be or can include electrodes. an
`ultraviolet ignition source. a capacitive ignition source. an
`inductive ignition source, an RF ignition source. a microwave
`ignition source. a llash lamp. a pulsed laser. or a pulsed lamp.
`The ignition source can he a continuous wave (CW) or pulsed
`laser impinging on a solid or liquid target in the chamber. The
`ignition source can be external or internal to the chamber.
`The light source can include at least one optical element for
`‘ modifying a property ofeleetromagnetic radiation emitted by
`the ionized gas. The optical element can be. for example. one
`or more mirrors or lenses. In some embodiments. the optical
`
`This application is a continuation ofU.S. Ser. No. 13/964,
`938, filed on Aug. 12, 2013. which is a continuation of U.S.
`Ser. No. l3/024,027, filed on Feb. 9, 201 l. now US, Pat. No.
`8.525.138, which claims the benefit of. and priority to U.S.
`Provisional Patent Application No. 61/302,797, filed on Feb.
`9. 2010, the entire disclosure of which is incorporated by
`reference herein, Ser. No. 13/024.027 is also a continuation-
`in-part ofU.S. Ser. No. 12/166,918. filed on Jul. 2, 2008. now
`U.S. Pat. No. 7,989,786. which is a continuation—in—part of
`U.S. Ser. No. l 1/695.348, filed onApr. 2, 2007. now US. Pat.
`No. 7.786,-455, which is a continuation-in-part of U.3. Ser.
`No. ll./395.523. filed on Mar. 31. 2006, now U.S. Pat. No.
`7,435,982. the entire disclosures of each ofwhich are hereby
`incorporated by reference herein.
`
`FIELD OF THE INVENTION
`
`The invention relates to methods and apparatus for provid-
`ing a laser—driven light source.
`
`BACKGROUND OF THE; lN\/l£N'l'lON
`
`High brightness light sources can be used in a variety of
`applications. For example. a high brightness light source can
`be used for inspection. testing or measuring properties asso-
`ciated with semiconductor waters or materials used in the
`fabrication of wafers (e.g.. reticles and photomasks). The
`electromagnetic energy produced by high brightness light
`sources can, alternatively, be used as a source ofillumination
`in a lithography system used in the fabrication of wafers, :1
`microscopy system. or a photoresist curing system. The
`parameters (e. g.. wavelength. power level and brightness) of
`the light vary depending upon the application.
`The state ofthc art in. for example. wafer inspection sys-
`tems involves the use of xenon or mercury arc lamps to
`produce light. The are lamps include an anode and cathode
`that are used to excite xenon or mercury gas located in a
`chamber of the lamp. An electrical discharge is generated
`between the anode and cathode to provide power to the
`excited ( ionized) gas to sustain the light emitted by the
`ionized gas during operation of the light source. During
`operation. the anode and cathode become very hot due to
`electrical discharge delivered to the ionized gas located
`between the anode and cathode. As a result. the anode and/’or
`cathode
`prone to wear and may emit particles that can
`contaminate the light‘ source or result in failure of the light
`source. Also. these are lamps do not provide sufiicient bright-
`ness for some applications. especially in the ultraviolet spec-
`trum. Further. the position oi‘ the arc can be unstable in these
`lamps.
`Accordingly. a need therelore exists for improved high
`brightness light sources. A need also exists for improved high
`brightness light sources that do not rely on an electrical dis-
`charge to maintain a plasma that generates a high brightness
`light.
`The properties of light produced by many light sources
`(e, g.. are lamps. microwave lamps) are aifec ted when the light
`passes through a wall of. for example. a chamber that includes
`the location from which the light is emitted.
`
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`US 8,969,841 B2
`
`3
`element is configured to deliverthe electromagnetic radiation
`emitted by the ionized gas to a tool (e.g._. a wafer inspection
`tool. a microscope. a metrology tool. a lithography tool. or an
`endoscopic tool).
`The invention, in another aspect. relates to a method for
`producing llflll. The method involves ionizing with an igni-
`tion source a gas within a chamber. The method also involves
`providing laser energy to the ionized gas in the chamber to
`produce a high brightness light.
`In some embodiments. the method also involves directing
`the laser energy through at least one optical element for
`modifying a property of the laser energy provided to the
`ionized gas. In some embodiments, the method also involves
`actively pumping the chamber. The ionizable medium can be
`a moving target. In some embodiments, the mediod also
`involves directing the high brightness light througi at least
`one optical element to modify a property ofthe light. In some
`embodiments, the method also involves delivering the high
`brightness light emitted by the ionized medium to a tool (eg..
`a wafer inspection tool. a microscope. u metrology tool, a
`lithography tool, or an endoscopic tool).
`In another aspect. the invention features a light source. The
`lights source includes a chamber and an ignition source for
`ionizing an ionizable medium within the chamber. The light
`source also includes at least one laser for providing substan-
`tially continuous energy to the ionized medium within the
`chamber to produce a high brightness light.
`In some embodiments. the at least one laser is a continuous
`wave laser or a high pulse rate laser. In some embodiments.
`the at least one laser is a high pulse rate laser that provides
`pulses ofenerg; to the ionized medium so the high brightness
`light is substantially continuous. In some embodiments. the
`magnitude of the high brightness light does not vary by more
`than about 90% during operation. In some embodiments, the
`at least one laser provides energy substantially continuously
`to minimize cooling of the ionized medium when energy is
`not provided to the ionized medium.
`In some embodiments, the light source can include at least
`one optical element (eg. a lens or mirror) for modifying a
`property of the laser energy provided to the ionized medium.
`The optical element can be. for example, an aplanatic lens, an
`achromatic lens. a single element lens. a frcsnel lens. a coated
`mirror, a dielectric coated mirror. a narrow band mirror. or an
`ultraviolet transparent infrared reflecting mirror.
`In some
`embodiments, the optical element is one or more fiber optic
`elements for directing the laser energy to the ionizable
`medium.
`In some embodiments. the chamber includes an ultraviolet
`transparent region. In some embodiments. the chamber or a
`window in the chamber includes a quartz material. suprasil
`quartz material. sapphire material, MgF3 material. diamond
`material. or Calfi material. In some embodiments. the cham-
`ber is a sealed chamber. The chamber can be capable ofbeing
`actively pumped.
`In some embodiments.
`the chamber
`includes a dielectric material
`quartz). In some embodi-
`ments. the chamber is a glass bulb. In some embodiments. the
`cliamber is an ultraviolet transparent dielectric chamber.
`The ionizable medium can be a solid. liquid or gas. The
`ionizable medium can include one or more olia noble gas. Xe.
`Ar. Ne.
`He. I)_,. I'll. 02, F_,. a metal halide. a halogen. Hg.
`Cd. Zn. Sn. Ga. Fe. Li. Na. an excimer forming gas. air. a
`vapor. a metal oxide. an aerosol. a flowing media. a recycled
`media. or an evaporating target. In some embodiments. the
`ionizable medium is a target in the chamber and the ignition
`source is a pulsed laser that provides a pulsed laser beam that
`strikes the target. The target can be a pool or film of metal. In
`some embodiments. the target is capable of moving.
`
`3
`
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`
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`
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`In some embodiments, the at least one laser is multiple
`diode lasers coupled into a fiber optic element. The at least
`one laser can emit at least one wavelength ofelectromagnetie
`energy that is strongly absorbed by the ionized medium.
`The ignition source can be or can include electrodes. an
`ultraviolet ignition source. a capacitive ignition source. an
`inductive ignition source. an
`ignition source. a microwave
`ignition source. a flash lamp. a pulsed laser. or a pulsed lamp.
`The ignition source can be external or internal to the chamber.
`In some embodiments, the light source includes at least one
`optical element (e.g.. a mirror or lens) for modifying a prop-
`erty of electromagnetic radiation emitted by the ionized
`medium. The optical element can be configured to deliver the
`electromagnetic radiation emitted by the ionized medium to a
`tool (e. g.. a wafer inspection tool. a microscope, a rnetrology
`tool. a lithography tool. or an endoscopic tool).
`The invention. in another aspect relates to a method for
`producing light. The method involves ionizing with an igni-
`tion source an ionizable medium within a chamber. The
`method also involves providing substantially continuous
`laser energy to the ionized medium in the chamber to produce
`a high brightness light.
`In some embodiments. the method also involves directing
`the laser energy through at least one optical element for
`modifying a property of the laser energy provided to the
`ionizable medium. The method also can involve actively
`pumping the chamber. In some embodiments, the ionizable
`medium is a moving target. ‘the ionizable medium can
`include a solid. liquid or gas. In some embodiments. the
`method also involves directing the high brightness light
`through at least one optical element to modify a property of
`the light. In some embodiments, the method also involves
`delivering the
`brigtness light emitted by the ionized
`medium to a tool.
`The invention. in another aspect. features a light source
`having a chamber. The light source includes a first ignition
`means for ionizing an ionizable medium within the chamber.
`The light source also includes a means for providing substan-
`tially continuous laser energy to the ionized medium Within
`the chamber.
`The invention, in another aspect, features a light source
`having a chamber that includes a reflective surface. The light
`source also includes an ignition source for ionizing a gas
`within the chamber. The light source also includes a reflector
`that at least substantially reflects a first set of predefined
`wavelengths of electromagnetic energy directed toward the
`reflector and at least substantially allows a second set of
`predefined wavelengths of electromagnetic energy to pass
`through the reflector. The light source also includes at least
`one laser (eg, a continuous-wave fiber laser) external to the
`chamber for providing electromagnetic energy to the ionized
`gas within the chamber to produce a plasma that generates a
`high brightness light. A continuous-vv‘ave laser emits radia-
`tion continuously or substantially continuously rather than in
`short bursts. as in a pulsed laser.
`In some embodirnents. at least one laser directs a lirst set of
`wavelengths olielectromagnelic energy through the reflector
`toward the re tlective surface (g.. inner surface) of the cham-
`ber and the relleetive surface directs at least a portion of the
`first set of wavelengths o T electromagnetic energy toward the
`plasma. In some embodiments. at least a portion of‘ the high
`brightness light is directed toward the reflective surface of the
`chamber. is reflected toward the reflector. and is reliected by
`the reflector toward a tool. In some embodiments. at least one
`laser directs a first set of wavelengths of electromagnetic
`energy toward the reflector.
`the rellector reflects at least a
`portion of the first wavelengths of electromagnetic energy
`
`
`
`US 8,969,841 B2
`
`5
`towards the reflective surface of the chamber, and the reflec-
`tive surface directs a portion of the first set of wavelengths of
`electromagnetic energy toward the plasma.
`In some embodiments. at least a portion ofthe high bright-
`ness light is directed toward the reflective surface of the
`chamber. is reflected toward the reflector. and passes through
`the reflector toward an output of the light source. In some
`embodiments, the light source comprises a microscope, ultra-
`violet microscope, wafer inspection system. reticle inspec-
`tion system or lithography system spaced relative to the out-
`put of the light source to receive the high brightness light. In
`some embodiments, a portion of the high brightness light is
`directed toward the reflective surface of the chamber.
`is
`reflected toward the reflector. and electromagnetic energy
`comprising the second set ofpredeflned wavelengths of elec-
`tromagnetic energy passes through the reflector.
`The chamber of the light source can include a window. In
`some embodiments. the chamber is a sealed chamber. In some
`embodiments, the reflective surface of the chamber com-
`prises a curved shape, parabolic shape, elliptical shape,
`spherical shape or aspherical shape. In some embodiments.
`the chamber has a reflective inner surface. In some embodi-
`ments, a coating or film is located on the outside of the
`chamber to produce the reflective surface. In some embodi-
`ments, a coating orfilm is located on the inside ofthe chamber
`to produce the reflective surface. In some embodiments. the
`reflective surface is a structure or optical element that is
`distinct from the inner surface of the chamber.
`The light source can include an optical element disposed
`along a path the electromagnetic energy from the laser travels.
`In some embodiments, the optical element is adapted to pro-
`vide electromagnetic energy from the laser to the plasma over
`a large solid angle. In some embodiments. the reflective sur-
`face of the chamber is adapted to provide electromagnetic
`energy from the laser to the plasma over a large solid angle. In
`some embodiments, the reflective surface of the chamber is
`adapted to collect the high brightness light generated by the
`plasma over a large solid angle. In some embodiments, one or
`more of the reflective surface. reflector and the window
`include (e.g._, are coated or include) a material to filter pre-
`defined wavelengths (e.g.. infrared wavelengths of electro-
`magnetic energy) of electromagnetic energy.
`The invention. in anothcraspcct. features a light sourcethat
`includes a chamber that has a reflective surface. The light
`source also includes an ignition source for ionizing a gas
`within the chamber. The light source also includes at least one
`laser external to the chamber for providing electromagnetic
`energy to the ionized gas within the chamber to produce a
`plasma that generates a high brightness light. The light source
`also includes a rellector positioned along a path that the
`electromagnetic energy travels from the at least one laser to
`the reflective surface of the chamber.
`In some embodiments. the reflector is adapted to at least
`substantially reflect a first set oil’ predefined wavelengths of
`electromagnetic energy directed toward the reflector and at
`least substantially allow a second set of predefined wave-
`lengths ofelectromagnetic energy to pass through the reflec-
`tor.
`
`The invention. in another aspect. relates to a method for
`producing light. The method involves ionizing with an igni-
`tion source a gas within a chamber that has a reflective sur-
`face. The method also involves providing laser energy to the
`ionized gas in the chamber to produce a plasma that generates
`a high brightness light.
`In some embodiments. the method involves directing the
`laser energy comprising a tlrst set of wavelengths of electro-
`magnetic energy through a reflector toward the reflective
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`surface of the chamber. the reflective surface refiecting at
`least a portion of the first set of wavelengths ofelectromag-
`netic enery toward the plasma. In some embodiments, the
`method involves directing at least a portion ofthe high bright-
`ness light toward the reflective surface of the chamber which
`is reflected toward the reflector and is reflected by the reflec-
`tor tow