`
`§§t§§§§e§»~we§§
`
`000000011078
`
`Version 2.3
`
`Revision Date 06/17/2014
`
`Print Date 12/12/2014
`
`SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
`
`Product name
`
`MSDS Number
`
`Product Use Description
`
`Manufacturer or suppliers
`details
`
`For more information call
`
`:
`
`I
`
`:
`
`:
`
`:
`
`So|stice® yf Refrigerant (R-1234yf)
`
`000000011078
`
`Refrigerant
`
`Honeywell International Inc.
`101 Columbia Road
`
`Morristown, NJ 07962-1057
`
`800-522-8001
`+1-973-455-6300
`
`(Monday-Friday, 9:00am-5:00pm)
`
`In case of emergency call
`
`: Medical: 1-800-498-5701 or +1-303-389-1414
`:
`Transportation (CHEMTREC): 1-800-424-9300 or +1-703-
`527-3887
`
`(24 hours/day, 7 days/week)
`
`SECTION 2. HAZARDS IDENTIFICATION
`
`Emergency Overview
`
`Form
`
`Color
`
`Odor
`
`: Liquefied gas
`
`: clear
`
`:
`
`slight
`
`Classification of the substance or mixture
`
`Classification of the
`substance or mixture
`
`: Flammable gases, Category 1
`Gases under pressure, Liquefied gas
`Simple Asphyxiant
`
`1 of 15
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`Arkema Exhibit 1143
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`
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`SAFETY DATA SHEET
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`§§§§§§s§§§~>'w§§§§
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`Y
`
`000000011078
`
`Version 2.3
`
`Revision Date 06/17/2014
`
`Print Date 12/12/2014
`
`GHS Label elements, including precautionary statements
`
`Symbo|(s)
`
`Signal word
`
`Hazard statements
`
`: Extremely flammable gas.
`Contains gas under pressure; may explode if heated.
`May displace oxygen and cause rapid suffocation.
`
`Precautionary statements
`
`2 Prevention:
`Keep away from heat/sparks/open flames/hot surfaces. - No
`smoking.
`
`Response:
`Leaking gas fire: Do not extinguish, unless leak can be stopped
`safely.
`Eliminate all ignition sources if safe to do so.
`
`Storage:
`Protect from sunlight. Store in a well-ventilated place.
`
`Hazards not othenlvise
`classified
`
`: May cause eye and skin irritation.
`May cause frostbite.
`
`Carcinogenicity
`
`No component of this product present at levels greater than or equal to 0.1% is identified as a known
`or anticipated carcinogen by NTP, IARC, or OSHA.
`
`SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
`
`Chemical nature
`
`: Substance
`
`Chemical Name
`
`CAS-No.
`
`Concentration
`
`2,3,3,3-Tetrafluoroprop-1-ene
`
`754-12-1
`
`100.00 %
`
`2ofl5
`
`
`
`SAFETY DATA SHEET
`
`§§ §§§se§~>ws§§
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`Y
`
`000000011078
`
`Version 2.3
`
`SECTION 4. FIRST AID MEASURES
`
`Revision Date 06/17/2014
`
`Print Date 12/12/2014
`
`General advice
`
`Inhalation
`
`Skin contact
`
`:
`
`First aider needs to protect himself. Take off all contaminated
`clothing immediately.
`
`: Remove to fresh air. If not breathing, give artificial respiration.
`If breathing is difficult, give oxygen. Use oxygen as required,
`provided a qualified operator is present. Call a physician.
`
`: After contact with skin, wash immediately with plenty of water.
`Rapid evapouration of the liquid may cause frostbite. If there is
`evidence of frostbite, bathe (do not rub) with lukewarm (not
`hot) water.
`If water is not available, cover with a clean, soft
`cloth or similar covering. Call a physician. Wash contaminated
`clothing before re-use.
`
`Eye contact
`
`: Rinse immediately with plenty of water. also under the eyelids,
`for at least 15 minutes. In case of frostbite water should be
`
`lukewarm, not hot. Call a physician.
`
`Ingestion
`
`Notes to physician
`
`: Unlikely route of exposure. As this product is a gas, refer to the
`inhalation section. Do not induce vomiting without medical
`advice. If conscious, drink plenty of water. Never give anything
`by mouth to an unconscious person. Call a physician
`immediately.
`
`Treatment
`
`: Treat frost-bitten areas as needed. Treat symptomatically.
`
`SECTION 5. FIREFIGHTING MEASURES
`
`Suitable extinguishing media
`
`:
`
`In case of tire, allow gas to burn if flow cannot be shut off
`immediately.
`Apply water from a safe distance to cool container and protect
`surrounding area.
`Use water spray, alcohol-resistant foam, dry chemical or
`carbon dioxide.
`
`Specific hazards during
`firefighting
`
`: Flammable gas.
`Contents under pressure.
`
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`SAFETY DATA SHEET
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`000000011078
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`Version 2.3
`
`Revision Date 06/17/2014
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`Print Date 12/12/2014
`
`Vapours are heavier than air and can cause suffocation by
`reducing oxygen available for breathing.
`Vapors may travel to areas away from work site before
`igniting/flashing back to vapor source.
`Fire or intense heat may cause violent rupture of packages.
`Cool closed containers exposed to fire with water spray.
`Do not allow run-off from fire fighting to enter drains or water
`courses.
`
`In case of fire hazardous decomposition products may be
`produced such as:
`Hydrogen fluoride
`Carbonyl halides
`Carbon monoxide
`
`Carbon dioxide (CO2)
`
`In the event of fire and/or explosion do not breathe fumes.
`Wear self-contained breathing apparatus and protective suit.
`No unprotected exposed skin areas.
`
`In case of fire: Evacuate area. Fight fire remotely due to the
`risk of explosion.
`
`Special protective equipment
`for firefighters
`
`Further information
`
`:
`
`:
`
`SECTION 6. ACCIDENTAL RELEASE MEASURES
`
`Personal precautions
`
`:
`
`lmmed iately evacuate personnel to safe areas.
`Keep people away from and upwind of spill/leak.
`Wear personal protective equipment. Unprotected persons
`must be kept away.
`Wear self-contained breathing apparatus and protective suit.
`Eliminate all ignition sources if safe to do so.
`Avoid skin contact with leaking liquid (danger of frostbite).
`Ventilate the area.
`
`Vapors may travel to areas away from work site before
`igniting/flashing back to vapor source.
`Vapours are heavier than air and can cause suffocation by
`reducing oxygen available for breathing.
`Avoid accumulation of vapours in low areas.
`Unprotected personnel should not return until air has been
`tested and determined safe.
`
`Ensure that the oxygen content is >= 19.5%.
`
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`000000011078
`
`Version 2.3
`
`Revision Date 06/17/2014
`
`Print Date 12/12/2014
`
`Environmental precautions
`
`:
`
`Prevent further leakage or spillage if safe to do so.
`The product evapourates readily.
`Discharge into the environment must be avoided.
`
`Methods for cleaning up
`
`: Use explosion-proof equipment.
`No sparking tools should be used.
`Ventilate the area.
`
`Allow to evapourate.
`
`SECTION 7. HANDLING AND STORAGE
`
`Handfing
`
`Handling
`
`Advice on protection
`against fire and explosion
`
`: Handle with care.
`Wear personal protective equipment.
`Do not breathe vapour.
`Avoid contact with skin, eyes and clothing.
`Use only in well-ventilated areas.
`Pressurized container. Protect from sunlight and do not expose
`to temperatures exceeding 50 °C.
`Follow all standard safety precautions for handling and use of
`compressed gas cylinders.
`Use authorized cylinders only.
`Protect cylinders from physical damage.
`Do not puncture or drop cylinders, expose them to open flame
`or excessive heat.
`
`Do not remove screw cap until immediately ready for use.
`Always replace cap after use.
`
`: Container hazardous when empty.
`Prevent the creation of flammable or explosive concentrations
`of vapour in air and avoid vapour concentration higher than the
`occupational exposure limits.
`Keep product and empty container away from heat and
`sources of ignition.
`Do not pressurize, cut, weld, braze, solder, drill, grind or
`expose containers to heat or sources of ignition.
`Take measures to prevent the build up of electrostatic charge.
`Electrical equipment should be protected to the appropriate
`standard.
`
`Use explosion-proof equipment.
`No sparking tools should be used.
`No smoking.
`
`5ofl5
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`SAFETY DATA SHEET
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`§§ §§§§e§~>w§%§§
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`000000011078
`
`Version 2.3
`
`Revision Date 06/17/2014
`
`Print Date 12/12/2014
`
`Storage
`
`Requirements for storage
`areas and containers
`
`: Pressurized container: protect from sunlight and do not expose
`to temperatures exceeding 50 °C. Do not pierce or burn, even
`after use.
`
`Keep containers tightly closed in a dry, cool and well-ventilated
`place.
`Keep away from heat and sources of ignition.
`Storage rooms must be properly ventilated.
`Ensure adequate ventilation, especially in confined areas.
`Protect cylinders from physical damage.
`Store away from incompatible substances.
`Store in original container.
`
`SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
`
`Protective measures
`
`: Ensure that eyewash stations and safety showers are close to
`the workstation location.
`
`Do not breathe vapour.
`Avoid contact with skin, eyes and clothing.
`
`Engineering measures
`
`: Use with local exhaust ventilation.
`
`Eye protection
`
`: Safety goggles
`
`Hand protection
`
`:
`
`Protective gloves
`Gloves must be inspected prior to use.
`Replace when worn.
`
`Skin and body protection
`
`: Avoid skin contact with leaking liquid (danger of frostbite).
`Wear suitable protective equipment.
`
`Respiratory protection
`
`Hygiene measures
`
`: No personal respiratory protective equipment normally
`required.
`When workers are facing concentrations above the exposure
`limit they must use appropriate certified respirators.
`Use NIOSH approved respiratory protection.
`
`: Handle in accordance with good industrial hygiene and safety
`practice.
`Ensure adequate ventilation, especially in confined areas.
`When using do not eat, drink or smoke.
`
`6ofl5
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`SAFETY DATA SHEET
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`§§t§§§§e§»~s<se§§
`
`000000011078
`
`Version 2.3
`
`Revision Date 06/17/2014
`
`Print Date 12/12/2014
`
`Ex osure Guidelines
`
`2,3,3,3-
`Tetrafl uoroprop-
`1-ene
`
`2,3,3,3-
`Tetrafluoroprop-
`1-ene
`
`2,3,3,3-
`Tetrafluoroprop-
`1-ene
`
`Remove and wash contaminated clothing before re-use.
`Keep working clothes separately.
`Do not breathe vapour.
`Avoid contact with skin, eyes and clothing.
`
`o . rameters
`
`te
`
`(500 ppm)
`
`2009 WEEL.US. AIHA
`Workplace
`Environmental
`Exposure Level
`(WEEL) Guides
`
`(1,500 ppm)
`
`Honeywe||:Limit
`established by
`Honeywell
`International Inc.
`
`Honeywe||:Limit
`established by
`Honeywell
`International Inc.
`
`TWA :
`time
`weighted
`average
`
`:
`
`time
`weighted
`average
`
`STEL I
`Short
`term
`exposure
`limit
`
`SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
`
`Physical state
`
`: Liquefied gas
`
`Color
`
`pH
`
`: clear
`
`:
`
`slight
`
`: Note: no data available
`
`Boiling point/boiling range
`
`:
`
`-29.4 °C
`
`Flash point
`
`: Note: not applicable
`
`7ofl5
`
`
`
`SAFETY DATA SHEET
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`§§ §§§§e§~>w§%§§
`
`I
`
`.3 lg:
`
`000000011078
`
`Version 2.3
`
`Revision Date 06/17/2014
`
`Print Date 12/12/2014
`
`Evaporation rate
`
`: Note: not determined
`
`lower flammability limit
`
`upper flammability limit
`
`Vapor pressure
`
`Vapor density
`
`Density
`
`Water solubility
`
`Partition ooefficient: n-
`octanol/water
`
`Ignition temperature
`
`:
`
`:
`
`:
`
`:
`
`:
`
`:
`
`:
`
`:
`
`6 %(V)
`
`12.3 %(V)
`
`6,067 hPa
`at 21.1 °C(70.0 °F)
`14,203 hPa
`at 54.4 °C(129.9 °F)
`
`4 Note: (Air = 1.0)
`
`1.1 g/cm3 at 25 °C
`
`198.2 mg/I at 24 °C
`
`Method: 92/69/EEC, A.6
`
`log Pow: 2.15
`Method: 92/69/EEC, A.8
`
`405 °C
`Method: Auto-ignition temperature
`
`Molecular weight
`
`: 114 g/mol
`
`SECTION 10. STABILITY AND REACTIVITY
`
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`SAFETY DATA SHEET
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`§§t§§§:~a§~>'we§§
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`000000011078
`
`Version 2.3
`
`Revision Date 06/17/2014
`
`Print Date 12/12/2014
`
`Chemical stability
`
`: Stable under normal conditions.
`
`Possibility of hazardous
`reactions
`
`Conditions to avoid
`
`: Hazardous polymerisation does not occur.
`
`: Keep away from heat and sources of ignition.
`Pressurized container. Protect from sunlight and do not
`expose to temperatures exceeding 50 °C.
`Do not pressurize, cut, weld, braze, solder, drill, grind or
`expose containers to heat or sources of ignition.
`Decomposes under high temperature.
`Some risk may be expected of corrosive and toxic
`decomposition products.
`
`Incompatible materials to
`avoid
`
`: Strong oxidizing agents
`Finely divided aluminium
`Finely divided magnesium
`Zinc
`
`Hazardous decomposition
`products
`
`:
`
`In case of fire hazardous decomposition products may be
`produced such as:
`Hydrogen fluoride
`Carbonyl halides
`Carbon monoxide
`
`Carbon dioxide (CO2)
`
`SECTION 11. TOXICOLOGICAL INFORMATION
`
`Acute inhalation toxicity
`
`: LC50: > 400000 ppm
`Exposure time: 4 h
`Species: rat
`
`Sensitisation
`
`: Cardiac sensitization
`
`Species: dogs
`Result: No effects observed for exposures up to 12% (120,189
`PW")-
`
`Repeated dose toxicity
`
`: Species: rat
`Application Route: Inhalation
`Exposure time: 2 Weeks
`No-observed-effect level: 50000 ppm
`
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`000000011078
`
`Version 2.3
`
`Revision Date 06/17/2014
`
`Print Date 12/12/2014
`
`: Species: rat
`Application Route: Inhalation
`Exposure time: 4 Weeks
`NOAEL (No observed adverse effect level):
`
`50000 ppm
`
`: Species: rat
`Application Route: Inhalation
`Exposure time: 13 Weeks
`NOAEL (No observed adverse effect level):
`
`50000 ppm
`
`: Species: rabbit, male
`Application Route: Inhalation
`Exposure time: 28 d
`No-observed-effect level: 500 ppm
`
`: Species: rabbit, female
`Application Route: Inhalation
`Exposure time: 28 d
`No-observed-effect level: 1000 ppm
`
`: Species: mini-pig
`Application Route: Inhalation
`Exposure time: 28 d
`NOAEL (No observed adverse effect level):
`Note: highest exposure tested
`
`10,000 ppm
`
`: Test Method: Ames test
`Result: 20% and higher, positive in TA 100 and e. coli WP2
`uvrA, negative in TA98, TA100, and TA1535.
`
`Test Method: Chromosome aberration test in vitro
`
`Cell type: Human lymphocytes
`Result: negative
`Note: Dose 760,000 ppm
`
`Test Method: Chromosome aberration test in vitro
`
`Cell type: Chinese Hamster Lung Cells
`Result: negative
`
`Genotoxicity in vitro
`
`Genotoxicity in vivo
`
`:
`
`Species: mouse
`Cell type: Micronucleus
`Dose: up to 200,000 ppm (4 hour)
`Result: negative
`
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`
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`000000011078
`
`Version 2.3
`
`Revision Date 06/17/2014
`
`Print Date 12/12/2014
`
`Genotoxicity in vivo
`
`: Test Method: Unscheduled DNA synthesis
`Dose: up to 50,000 ppm (4 weeks)
`Result: negative
`
`Genotoxicity in vivo
`
`:
`
`Species: rat
`Cell type: Micronucleus
`Dose: up to 50,000 ppm (4 weeks)
`Result: negative
`
`Reproductive toxicity
`
`: Species: rat
`Application Route: Inhalation exposure
`Exposure time: Two-generation reproductive toxicity
`NOAEL,parent: 50,000 ppm
`NOAEL,F1: 50,000 ppm
`NOAEL,F2: 50,000 ppm
`
`Teratogenicity
`
`: Species: rat
`Dose: NOAEL (No observed adverse effect level) - 50,000
`Ppm
`
`: Species: rabbit
`Dose: NOAEL (No observed adverse effect level) - 4,000 ppm
`
`SECTION 12. ECOLOGICAL INFORMATION
`
`Ecotoxicity effects
`
`Toxicity to fish
`
`: LC50: > 197 mg/I
`Exposure time: 96 h
`Species: Cyprinus oarpio (Carp)
`Method: OECD Test Guideline 203
`Note: No demonstrable toxic effect in saturated solution.
`
`Toxicity to daphnia and other
`aquatic invertebrates
`
`: EC50: > 83 mg/I
`Exposure time: 48 h
`Species: Daphnia magna (Water flea)
`Method: OECD Test Guideline 202
`
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`SAFETY DATA SHEET
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`000000011078
`
`Version 2.3
`
`Revision Date 06/17/2014
`
`Print Date 12/12/2014
`
`Toxicity to algae
`
`: EC50: > 100 mg/I
`Species: Scenedesmus capricornutum (fresh water algae)
`
`Elimination information (persistence and degradability)
`
`Biodegradability
`
`: Result: Not readily biodegradable.
`
`Further information on ecology
`
`SECTION 13. DISPOSAL CONSIDERATIONS
`
`Disposal methods
`
`: Observe all Federal, State, and Local Environmental
`regulations.
`
`SECTION 14. TRANSPORT INFORMATION
`
`DOT
`
`UN/ID No.
`
`: UN 3161
`
`Proper shipping name
`
`Class
`
`Packing group
`Hazard Labels
`
`: LIQUEFIED GAS, FLAMMABLE, N.O.S.
`( R-1234yf)
`2.1
`
`2.1
`
`UN/ID No.
`
`: UN 3161
`
`Description of the goods
`
`Class
`Hazard Labels
`
`: LIQUEFIED GAS, FLAMMABLE, N.O.S.
`( R-1234yf)
`2 2.1
`2 2.1
`
`Packing instruction (cargo
`aircraft)
`
`: 200
`
`UN/ID No.
`
`: UN 3161
`
`Description of the goods
`
`Class
`Hazard Labels
`
`EmS Number
`
`: LIQUEFIED GAS, FLAMMABLE, N.O.S.
`( R-1234yf)
`: 2.1
`: 2.1
`
`: F-D, S-U
`
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`000000011078
`
`Version 2.3
`
`Revision Date 06/17/2014
`
`Print Date 12/12/2014
`
`Marine pollutant
`
`SECTION 15. REGULATORY INFORMATION
`
`Inventories
`
`US. Toxic Substances
`Control Act
`
`: On TSCA Inventory
`
`Australia. Industrial
`Chemical (Notification and
`Assessment) Act
`
`Canada. Canadian
`Environmental Protection
`
`Act (CEPA). Domestic
`Substances List (DSL)
`
`Japan. Kashin-Hou Law
`List
`
`Korea. Toxic Chemical
`Control Law (TCCL) List
`
`Philippines. The Toxic
`Substances and Hazardous
`and Nuclear Waste Control
`Act
`
`China. Inventory of Existing
`Chemical Substances
`
`New Zealand. Inventory of
`Chemicals (NZloC), as
`published by ERMA New
`Zealand
`
`: Not in compliance with the inventory
`
`754-12-1
`: 2,3,3,3-Tetrafluoroprop-1-ene
`: All components of this product are on the Canadian DSL.
`
`: On the inventory, or in compliance with the inventory
`
`: On the inventory, or in compliance with the inventory
`
`: Not in compliance with the inventory
`
`: 2,3,3,3-Tetrafluoroprop-1-ene
`: Not in compliance with the inventory
`
`754-12-1
`
`: 2,3,3,3-Tetrafluoroprop-1-ene
`: Not in compliance with the inventory
`
`754-12-1
`
`TSCA 12B
`
`754-12-1
`: 2,3,3,3-Tetrafluoroprop-1-ene
`: US. Toxic Substances Control Act (TSCA) Section 12(b) Export
`Notification (40 CFR 707, Subpt D)
`
`Page 13/15
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`SAFETY DATA SHEET
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`§§i§§§§e§~>we§§
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`000000011078
`
`Version 2.3
`
`Revision Date 06/17/2014
`
`Print Date 12/12/2014
`
`2,3,3,3-Tetrafluoroprop-1-ene
`
`754-12-1
`
`National regulatory information
`
`US. Toxic Substances
`
`Control Act (TSCA) Section
`5(a)(2) Final Significant
`New Use Rules (SNURS)
`(40 CFR 721, Subpt E)
`
`: 2,3,3,3-Tetrafluoroprop-1-ene
`
`754-12-1
`
`SARA 302 Components
`
`: SARA 302: No chemicals in this material are subject to the
`reporting requirements of SARA Title III, Section 302.
`
`SARA 313 Components
`
`: SARA 313: This material does not contain any chemical
`components with known CAS numbers that exceed the
`threshold (De Minimis) reporting levels established by SARA
`Title III, Section 313.
`
`SARA 311/312 Hazards
`
`: Fire Hazard
`Acute Health Hazard
`Sudden Release of Pressure Hazard
`
`California Prop. 65
`
`: This product does not contain any chemicals known to State of
`California to cause cancer, birth defects, or any other
`reproductive harm.
`
`New Jersey RTK
`
`: 2,3,3,3-Tetrafluoroprop-1-ene
`
`754-12-1
`
`Pennsylvania RTK
`
`: 2,3,3,3-Tetrafluoroprop-1-ene
`
`754-12-1
`
`WHMIS Classification
`
`: B1’ Flammable gas
`A‘ Compressed Gas
`This product has been classified according to the hazard criteria
`of the CPR and the MSDS contains all of the information
`
`required by the CPR.
`
`Page 14/ 15
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`§§ §§§§e§~s<se§§
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`000000011078
`
`Version 2.3
`
`Revision Date 06/17/2014
`
`Print Date 12/12/2014
`
`SECTION 16. OTHER INFORMATION
`
`Health hazard
`
`Flammability
`Physical Hazard
`Instability
`
`HMISIII
`: O
`
`NFPA
`2
`
`: 2
`: 2
`:
`
`2
`
`0
`
`Hazard rating and rating systems (e.g. HMIS® III, NFPA): This information is intended solely for the
`use of individuals trained in the particular system.
`
`Further information
`
`The information provided in this Safety Data Sheet is correct to the best of our knowledge,
`information and belief at the date of its publication. The information given is designed only as a
`guidance for safe handling, use, processing, storage, transportation, disposal and release and is not
`to be considered a warranty or quality specification. The information relates only to the specific
`material designated and may not be valid for such material used in combination with any other
`materials or in any process, unless specified in the text. Final determination of suitability of any
`material is the sole responsibility of the user. This information should not constitute a guarantee for
`any specific product properties.
`
`Changes since the last version are highlighted in the margin. This version replaces all previous
`versions.
`Previous Issue Date: 04/29/2014
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`Prepared by Honeywell Performance Materials and Technologies Product Stewardship Group
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`Page 15/15
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`15 of 15