SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`SECTION 1. IDENTIFICATION
`
`Product name
`
`Product code
`
`
`: DOW CORNING(R) 3179 DILATANT COMPOUND
`
`: 000000000001624032
`
`
`Manufacturer or supplier's details
`
`Company name of supplier
`
`Address
`
`
`Telephone
`
`Emergency telephone
`
`
`: Dow Corning Corporation
`
`: South Saginaw Road
`Midland Michigan 48686
`
`(989) 496-6000
`
`: 24 Hour Emergency Telephone : (989) 496-5900
`CHEMTREC : (800) 424-9300
`
`
`:
`
`Recommended use of the chemical and restrictions on use
`
`Recommended use
`
`
`: Lubricants and lubricant additives
`
`
`SECTION 2. HAZARDS IDENTIFICATION
`
`GHS classification in accordance with 29 CFR 1910.1200
`
`Reproductive toxicity
`
`
`GHS label elements
`
`Hazard pictograms
`
`
`Signal Word
`
`Hazard Statements
`
`Precautionary Statements
`
`
`: Category 2
`
`:
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`: Warning
`
`: H361f Suspected of damaging fertility.
`
`
`:
`
`Prevention:
`
`P201 Obtain special instructions before use.
`P202 Do not handle until all safety precautions have been read
`and understood.
`P280 Wear protective gloves/ protective clothing/ eye protection/
`face protection.
`
`Response:
`
`P308 + P313 IF exposed or concerned: Get medical advice/
`attention.
`
`Storage:
`
`P405 Store locked up.
`
`1 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 1 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`Disposal:
`
`P501 Dispose of contents/ container to an approved waste dis-
`posal plant.
`
`
`Other hazards
`
`None known.
`
`SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
`
`Substance / Mixture
`
`Chemical nature
`
`
`: Mixture
`
`: Silicone compound
`
`
`Hazardous ingredients
`
`Chemical name
`Quartz
`Titanium dioxide
`Glycerine
`Octamethylcyclotetrasiloxane
`
`
`
`SECTION 4. FIRST AID MEASURES
`
`CAS-No.
`14808-60-7
`13463-67-7
`56-81-5
`556-67-2
`
`Concentration (% w/w)
`>= 13 - <= 19
`>= 1 - <= 1.4
`>= 0.9 - <= 1.2
`>= 0.82 - <= 1.1
`
`General advice
`
`
`If inhaled
`
`
`In case of skin contact
`
`
`In case of eye contact
`
`
`If swallowed
`
`
`Most important symptoms
`and effects, both acute and
`delayed
`
`Protection of first-aiders
`
`
`:
`
`:
`
`:
`
`In the case of accident or if you feel unwell, seek medical
`advice immediately.
`When symptoms persist or in all cases of doubt seek medical
`advice.
`
`If inhaled, remove to fresh air.
`Get medical attention.
`
`In case of contact, immediately flush skin with soap and plenty
`of water.
`Remove contaminated clothing and shoes.
`Get medical attention.
`Wash clothing before reuse.
`Thoroughly clean shoes before reuse.
`
`: Flush eyes with water as a precaution.
`Get medical attention if irritation develops and persists.
`
`If swallowed, DO NOT induce vomiting.
`Get medical attention.
`Rinse mouth thoroughly with water.
`
`: Suspected of damaging fertility.
`
`
`:
`
`: First Aid responders should pay attention to self-protection,
`and use the recommended personal protective equipment
`
`2 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 2 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`Notes to physician
`
`
`when the potential for exposure exists.
`
`: Treat symptomatically and supportively.
`
`
`SECTION 5. FIRE-FIGHTING MEASURES
`
`Suitable extinguishing media
`
`
`Unsuitable extinguishing
`media
`
`Specific hazards during fire
`fighting
`
`Hazardous combustion prod-
`ucts
`
`
`Specific extinguishing meth-
`ods
`
`
`Special protective equipment
`for fire-fighters
`
`
`: Water spray
`Alcohol-resistant foam
`Carbon dioxide (CO2)
`Dry chemical
`
`: None known.
`
`
`: Exposure to combustion products may be a hazard to health.
`
`
`: Boron oxides
`Carbon oxides
`Silicon oxides
`Formaldehyde
`Metal oxides
`
`: Use extinguishing measures that are appropriate to local cir-
`cumstances and the surrounding environment.
`Use water spray to cool unopened containers.
`Remove undamaged containers from fire area if it is safe to do
`so.
`Evacuate area.
`
`In the event of fire, wear self-contained breathing apparatus.
`Use personal protective equipment.
`
`
`:
`
`SECTION 6. ACCIDENTAL RELEASE MEASURES
`
`Personal precautions, protec-
`tive equipment and emer-
`gency procedures
`
`Environmental precautions
`
`
`Methods and materials for
`containment and cleaning up
`
`
`: Use personal protective equipment.
`Follow safe handling advice and personal protective
`equipment recommendations.
`
`: Discharge into the environment must be avoided.
`Prevent further leakage or spillage if safe to do so.
`Prevent spreading over a wide area (e.g., by containment or
`oil barriers).
`Retain and dispose of contaminated wash water.
`Local authorities should be advised if significant spillages
`cannot be contained.
`
`: Soak up with inert absorbent material.
`For large spills, provide diking or other appropriate
`containment to keep material from spreading. If diked material
`can be pumped, store recovered material in appropriate
`container.
`
`3 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 3 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`Clean up remaining materials from spill with suitable
`absorbent.
`Local or national regulations may apply to releases and
`disposal of this material, as well as those materials and items
`employed in the cleanup of releases. You will need to
`determine which regulations are applicable.
`Sections 13 and 15 of this SDS provide information regarding
`certain local or national requirements.
`
`
`SECTION 7. HANDLING AND STORAGE
`
`Technical measures
`
`
`Local/Total ventilation
`
`Advice on safe handling
`
`
`Conditions for safe storage
`
`
`Materials to avoid
`
`
`: See Engineering measures under EXPOSURE
`CONTROLS/PERSONAL PROTECTION section.
`
`: Use only with adequate ventilation.
`
`: Avoid inhalation of vapor or mist.
`Do not swallow.
`Avoid contact with eyes.
`Avoid prolonged or repeated contact with skin.
`Handle in accordance with good industrial hygiene and safety
`practice, based on the results of the workplace exposure
`assessment
`Take care to prevent spills, waste and minimize release to the
`environment.
`
`: Keep in properly labeled containers.
`Store in accordance with the particular national regulations.
`
`: Do not store with the following product types:
`Strong oxidizing agents
`
`
`SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
`
`Ingredients with workplace control parameters
`
`Ingredients
`
`CAS-No.
`
`Quartz
`
`14808-60-7
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`Titanium dioxide
`
`13463-67-7
`
`Value type
`(Form of
`exposure)
`TWA (respir-
`able)
`TWA (respir-
`able)
`TWA (Res-
`pirable frac-
`tion)
`TWA (Res-
`pirable dust)
`TWA (Res-
`pirable dust)
`TWA (total
`dust)
`
`Control parame-
`ters / Permissible
`concentration
`10 mg/m3
`/ %SiO2+2
`250 mppcf
`/ %SiO2+5
`0.025 mg/m³
`(Silica)
`
`Basis
`
`OSHA Z-3
`
`OSHA Z-3
`
`ACGIH
`
`0.05 mg/m³
`(Silica)
`0.05 mg/m³
`
`NIOSH REL
`
`OSHA Z-1
`
`15 mg/m³
`
`OSHA Z-1
`
`4 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 4 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`TWA
`
`Glycerine
`
`56-81-5
`
`
`
`
`
`Octamethylcyclotetrasiloxane
`
`556-67-2
`
`TWA (mist,
`respirable
`fraction)
`TWA (mist,
`total dust)
`TWA
`
`10 mg/m³
`(Titanium dioxide)
`5 mg/m³
`
`ACGIH
`
`OSHA Z-1
`
`15 mg/m³
`
`OSHA Z-1
`
`10 ppm
`
`US WEEL
`
`These substance(s) are inextricably bound in the product and therefore do not contribute
`to a dust inhalation hazard.
`
`Quartz
`
`Titanium dioxide
`
`Engineering measures
`
`: Processing may form hazardous compounds (see section
`10).
`Ensure adequate ventilation, especially in confined areas.
`Minimize workplace exposure concentrations.
`Dust formation may be relevant in the processing of this
`product. In addition to substance-specific OELs, general
`limitations of concentrations of particulates in the air at
`workplaces have to be considered in workplace risk
`assessment. Relevant limits include: OSHA PEL for
`Particulates Not Otherwise Regulated of 15 mg/m3 - total
`dust, 5 mg/m3 - respirable fraction; and ACGIH TWA for
`Particles (insoluble or poorly soluble) Not Otherwise
`Specified of 3 mg/m3 - respirable particles, 10 mg/m3 -
`inhalable particles.
`
`
`Personal protective equipment
`
`Respiratory protection
`
`
`: General and local exhaust ventilation is recommended to
`maintain vapor exposures below recommended limits. Where
`concentrations are above recommended limits or are
`unknown, appropriate respiratory protection should be worn.
`Follow OSHA respirator regulations (29 CFR 1910.134) and
`use NIOSH/MSHA approved respirators. Protection provided
`by air purifying respirators against exposure to any
`hazardous chemical is limited. Use a positive pressure air
`supplied respirator if there is any potential for uncontrolled
`release, exposure levels are unknown, or any other
`circumstance where air purifying respirators may not provide
`adequate protection.
`
`
`Hand protection
`
`Material
`
`: Chemical-resistant gloves
`
`Remarks
`
`
`
`: Choose gloves to protect hands against chemicals depending
`on the concentration specific to place of work. Breakthrough
`time is not determined for the product. Change gloves often!
`
`5 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 5 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`Eye protection
`
`
`Skin and body protection
`
`
`Hygiene measures
`
`
`For special applications, we recommend clarifying the
`resistance to chemicals of the aforementioned protective
`gloves with the glove manufacturer. Wash hands before
`breaks and at the end of workday.
`
`: Wear the following personal protective equipment:
`Safety glasses
`
`: Select appropriate protective clothing based on chemical
`resistance data and an assessment of the local exposure
`potential.
`Skin contact must be avoided by using impervious protective
`clothing (gloves, aprons, boots, etc).
`
`: Ensure that eye flushing systems and safety showers are
`located close to the working place.
`When using do not eat, drink or smoke.
`Wash contaminated clothing before re-use.
`These precautions are for room temperature handling. Use at
`elevated temperature or aerosol/spray applications may
`require added precautions.
`For further information regarding the use of silicones /
`organic oils in consumer aerosol applications, please refer to
`the guidance document regarding the use of these type of
`materials in consumer aerosol applications that has been
`developed by the silicone industry (www.SEHSC.com) or
`contact the Dow Corning customer service group.
`
`
`SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
`
`Appearance
`
`Color
`
`Odor
`
`Odor Threshold
`
`pH
`
`Melting point/freezing point
`
`Initial boiling point and boiling
`range
`
`Flash point
`
`
`Evaporation rate
`
`Flammability (solid, gas)
`
`Flammability (liquids)
`
`: viscous liquid
`
`: pink
`
`: none
`
`: No data available
`
`: No data available
`
`: No data available
`
`: > 100 °C
`
`
`: > 93.8 °C
`Method: closed cup
`
`: No data available
`
`: Not applicable
`
`: Not applicable
`
`6 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 6 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`
`
`Self-ignition
`
`Upper explosion limit / Upper
`flammability limit
`
`Lower explosion limit / Lower
`flammability limit
`
`Vapor pressure
`
`Relative vapor density
`
`Relative density
`
`Solubility(ies)
`Water solubility
`
`
`Partition coefficient: n-
`octanol/water
`
`Autoignition temperature
`
`Decomposition temperature
`
`Viscosity
`Viscosity, kinematic
`
`
`
`
`
`
`Explosive properties
`
`Oxidizing properties
`
`Molecular weight
`
`Particle size
`
`
`
`: The substance or mixture is not classified as pyrophoric. The
`substance or mixture is not classified as self heating.
`
`: No data available
`
`
`: No data available
`
`
`: No data available
`
`: No data available
`
`: 1.14
`
`
`: No data available
`
`: No data available
`
`
`: No data available
`
`: No data available
`
`
`: 10 m²/s (25 °C)
`
`
`
`
`
`: Not explosive
`
`: The substance or mixture is not classified as oxidizing.
`
`: No data available
`
`: Not applicable
`
`
`SECTION 10. STABILITY AND REACTIVITY
`
`Reactivity
`
`Chemical stability
`
`Possibility of hazardous reac-
`tions
`
`
`Conditions to avoid
`
`
`: Not classified as a reactivity hazard.
`
`: Stable under normal conditions.
`
`: Use at elevated temperatures may form highly hazardous
`compounds.
`Can react with strong oxidizing agents.
`Hazardous decomposition products will be formed at elevated
`temperatures.
`
`: None known.
`
`
`7 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 7 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`Incompatible materials
`
`
`: Oxidizing agents
`
`
`Hazardous decomposition products
`Thermal decomposition
`: Formaldehyde
`
`
`
`SECTION 11. TOXICOLOGICAL INFORMATION
`
`Information on likely routes of exposure
`
`Inhalation
`Skin contact
`Ingestion
`Eye contact
`
`Acute toxicity
`
`Not classified based on available information.
`
`Ingredients:
`
`Quartz:
`
`Acute oral toxicity
`
`
`Titanium dioxide:
`
`Acute oral toxicity
`
`Acute inhalation toxicity
`
`
`: LD50 (Rat): > 5,000 mg/kg
`
`
`: LD50 (Rat): > 5,000 mg/kg
`
`: LC50 (Rat): > 6.82 mg/l
`Exposure time: 4 h
`Test atmosphere: dust/mist
`Assessment: The substance or mixture has no acute inhala-
`tion toxicity
`
`
`Glycerine:
`
`Acute oral toxicity
`
`
`: LD50 (Rat): > 5,000 mg/kg
`
`
`Octamethylcyclotetrasiloxane:
`
`Acute oral toxicity
`
`
`Acute inhalation toxicity
`
`
`Acute dermal toxicity
`
`
`: LD50 (Rat): > 4,800 mg/kg
`Assessment: The substance or mixture has no acute oral tox-
`icity
`Remarks: On basis of test data.
`
`: LC50 (Rat): 2975 ppm
`Exposure time: 4 h
`Test atmosphere: vapor
`Assessment: The substance or mixture has no acute inhala-
`tion toxicity
`Remarks: On basis of test data.
`
`: LD50 (Rabbit): > 2.5 ml/kg
`Assessment: The substance or mixture has no acute dermal
`toxicity
`Remarks: On basis of test data.
`
`8 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 8 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`Skin corrosion/irritation
`
`Not classified based on available information.
`
`
`
`Ingredients:
`
`Titanium dioxide:
`
`Species: Rabbit
`Result: No skin irritation
`
`
`Glycerine:
`
`Result: No skin irritation
`
`
`Octamethylcyclotetrasiloxane:
`
`Species: Rabbit
`Result: No skin irritation
`Remarks: On basis of test data.
`
`
`Serious eye damage/eye irritation
`
`Not classified based on available information.
`
`Ingredients:
`
`Titanium dioxide:
`
`Species: Rabbit
`Result: No eye irritation
`
`
`Glycerine:
`
`Result: No eye irritation
`
`
`Octamethylcyclotetrasiloxane:
`
`Species: Rabbit
`Result: No eye irritation
`Remarks: On basis of test data.
`
`
`Respiratory or skin sensitization
`
`Skin sensitization
`
`Not classified based on available information.
`
`Respiratory sensitization
`
`Not classified based on available information.
`
`Ingredients:
`
`Titanium dioxide:
`
`Test Type: Local lymph node assay (LLNA)
`Routes of exposure: Skin contact
`Species: Mouse
`Result: negative
`
`9 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 9 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`
`
`Octamethylcyclotetrasiloxane:
`
`Assessment: Does not cause skin sensitization.
`
`Test Type: Maximization Test
`Species: Guinea pig
`Result: negative
`Remarks: On basis of test data.
`
`
`Germ cell mutagenicity
`
`Not classified based on available information.
`
`Ingredients:
`
`Titanium dioxide:
`
`Genotoxicity in vitro
`
`
`Genotoxicity in vivo
`
`
`Glycerine:
`
`Genotoxicity in vitro
`
`
`: Test Type: Bacterial reverse mutation assay (AMES)
`Result: negative
`
`: Test Type: In vivo micronucleus test
`Species: Mouse
`Result: negative
`
`
`: Test Type: In vitro mammalian cell gene mutation test
`Method: OECD Test Guideline 476
`Result: negative
`
`
`Octamethylcyclotetrasiloxane:
`
`Genotoxicity in vitro
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`Genotoxicity in vivo
`
`: Test Type: Bacterial reverse mutation assay (AMES)
`Result: negative
`Remarks: On basis of test data.
`
` Test Type: Mutagenicity (in vitro mammalian cytogenetic test)
`Result: negative
`Remarks: On basis of test data.
`
` Test Type: Chromosome aberration test in vitro
`Result: negative
`Remarks: On basis of test data.
`
` Test Type: In vitro sister chromatid exchange assay in mam-
`malian cells
`Result: negative
`Remarks: On basis of test data.
`
` Test Type: DNA damage and repair, unscheduled DNA syn-
`thesis in mammalian cells (in vitro)
`Result: negative
`Remarks: On basis of test data.
`
`: Test Type: Mammalian erythrocyte micronucleus test (in vivo
`
`10 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 10 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`
`
`
`
`
`Germ cell mutagenicity -
`Assessment
`
`
`Carcinogenicity
`
`cytogenetic assay)
`Species: Rat
`Application Route: inhalation (vapor)
`Result: negative
`Remarks: On basis of test data.
`
` Test Type: Rodent dominant lethal test (germ cell) (in vivo)
`Species: Rat
`Application Route: Ingestion
`Result: negative
`Remarks: On basis of test data.
`
`: Animal testing did not show any mutagenic effects.
`
`
`Not classified based on available information.
`
`Ingredients:
`
`Quartz:
`
`Species: Humans
`Application Route: inhalation (dust/mist/fume)
`Result: positive
`Remarks: IARC: (International Agency for Research on Cancer)
`These substance(s) are inextricably bound in the product and therefore do not contribute to a
`dust inhalation hazard.
`
`Carcinogenicity - Assess-
`ment
`
`
`: Positive evidence from human epidemiological studies (inhala-
`tion)
`
`
`Titanium dioxide:
`
`Species: Rat
`Application Route: inhalation (dust/mist/fume)
`Exposure time: 24 Months
`Method: OECD Test Guideline 453
`Result: positive
`Remarks: The mechanism or mode of action may not be relevant in humans.
`These substance(s) are inextricably bound in the product and therefore do not contribute to a
`dust inhalation hazard.
`
`Carcinogenicity - Assess-
`ment
`
`
`: Limited evidence of carcinogenicity in inhalation studies with
`animals.
`
`
`Glycerine:
`
`Species: Rat
`Application Route: Ingestion
`Exposure time: 2 Years
`Result: negative
`
`IARC
`
`
`Group 1: Carcinogenic to humans
`
`
`11 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 11 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`
`
`
`
`
`
`OSHA
`
`
`NTP
`
`
`
`14808-60-7
`Quartz
`
`
`Group 2B: Possibly carcinogenic to humans
`
`13463-67-7
`Titanium dioxide
`
`
`No component of this product present at levels greater than or
`equal to 0.1% is on OSHA’s list of regulated carcinogens.
`
`Known to be human carcinogen
`
`Quartz
`
`
`14808-60-7
`
`
`Reproductive toxicity
`
`Suspected of damaging fertility.
`
`Ingredients:
`
`Glycerine:
`
`Effects on fertility
`
`
`Effects on fetal development
`
`
`: Test Type: Two-generation reproduction toxicity study
`Species: Rat
`Application Route: Ingestion
`Result: negative
`
`: Test Type: Embryo-fetal development
`Species: Rabbit
`Application Route: Ingestion
`Result: negative
`
`
`Octamethylcyclotetrasiloxane:
`
`Effects on fertility
`
`
`Effects on fetal development
`
`
`Reproductive toxicity - As-
`sessment
`
`
`STOT-single exposure
`
`: Test Type: Two-generation reproduction toxicity study
`Species: Rat, male and female
`Application Route: inhalation (vapor)
`Symptoms: Effects on fertility.
`Remarks: On basis of test data.
`
`: Test Type: Prenatal development toxicity study (teratogenicity)
`Species: Rabbit
`Application Route: inhalation (vapor)
`Symptoms: No effects on fetal development.
`Remarks: On basis of test data.
`
`: Some evidence of adverse effects on sexual function and
`fertility, based on animal experiments.
`
`
`Not classified based on available information.
`
`STOT-repeated exposure
`
`Not classified based on available information.
`
`12 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 12 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`Ingredients:
`
`Quartz:
`
`Routes of exposure: inhalation (dust/mist/fume)
`Target Organs: Lungs
`Assessment: Shown to produce significant health effects in animals at concentrations of 0.02
`mg/l/6h/d or less.
`
`
`Octamethylcyclotetrasiloxane:
`
`Routes of exposure: Ingestion
`Assessment: No significant health effects observed in animals at concentrations of 100 mg/kg
`bw or less.
`
`Routes of exposure: inhalation (vapor)
`Assessment: No significant health effects observed in animals at concentrations of 1 mg/l/6h/d or
`less.
`
`Routes of exposure: Skin contact
`Assessment: No significant health effects observed in animals at concentrations of 200 mg/kg
`bw or less.
`
`
`Repeated dose toxicity
`
`Ingredients:
`
`Quartz:
`
`Species: Humans
`LOAEL: 0.053 mg/m³
`Application Route: Inhalation
`Remarks: These substance(s) are inextricably bound in the product and therefore do not
`contribute to a dust inhalation hazard.
`
`
`Titanium dioxide:
`
`Species: Rat
`NOAEL: 24,000 mg/kg
`Application Route: Ingestion
`Exposure time: 28 Days
`
`Species: Rat
`NOAEL: 10 mg/m³
`Application Route: inhalation (dust/mist/fume)
`Exposure time: 2 y
`Remarks: These substance(s) are inextricably bound in the product and therefore do not
`contribute to a dust inhalation hazard.
`
`
`Glycerine:
`
`Species: Rat
`NOAEL: 167 mg/m³
`LOAEL: 660 mg/m³
`Application Route: inhalation (dust/mist/fume)
`Exposure time: 13 Weeks
`
`13 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 13 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`Symptoms: Local irritation
`
`
`Octamethylcyclotetrasiloxane:
`
`Species: Rat
`Application Route: Ingestion
`Remarks: On basis of test data.
`
`Species: Rat
`Application Route: inhalation (vapor)
`Remarks: On basis of test data.
`
`Species: Rabbit
`Application Route: Skin contact
`Remarks: On basis of test data.
`
`
`Aspiration toxicity
`
`Not classified based on available information.
`
`Product:
`
`No aspiration toxicity classification
`
`
`Further information
`
`Ingredients:
`
`Octamethylcyclotetrasiloxane:
`
`Remarks: Results from a 2 year repeated vapor inhalation exposure study to rats of octamethyl-
`cyclotetrasiloxane (D4) indicate effects (benign uterine adenomas) in the uterus of female ani-
`mals. This finding occurred at the highest exposure dose (700 ppm) only. Studies to date have
`not demonstrated if these effects occur through pathways that are relevant to humans. Repeated
`exposure in rats to D4 resulted in protoporphyrin accumulation in the liver. Without knowledge of
`the specific mechanism leading to the protoporphyrin accumulation the relevance of this finding
`to humans is unknown.
`
`
`SECTION 12. ECOLOGICAL INFORMATION
`
`Ecotoxicity
`
`Ingredients:
`
`Quartz:
`
`Ecotoxicology Assessment
`
`Acute aquatic toxicity
`
`Chronic aquatic toxicity
`
`
`: No toxicity at the limit of solubility.
`
`: No toxicity at the limit of solubility.
`
`
`Titanium dioxide:
`
`Toxicity to fish
`
`
`: LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l
`Exposure time: 96 h
`
`14 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 14 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`Toxicity to daphnia and other
`aquatic invertebrates
`
`Toxicity to algae
`
`
`Toxicity to microorganisms
`
`
`Glycerine:
`
`Toxicity to fish
`
`
`Toxicity to daphnia and other
`aquatic invertebrates
`
`Toxicity to microorganisms
`
`
`Method: OECD Test Guideline 203
`
`: EC50 (Daphnia magna (Water flea)): > 100 mg/l
`Exposure time: 48 h
`
`: EC50 (Skeletonema costatum (marine diatom)): > 10,000 mg/l
`Exposure time: 72 h
`
`: EC50: > 1,000 mg/l
`Exposure time: 3 h
`Method: OECD Test Guideline 209
`
`
`: LC50 (Oncorhynchus mykiss (rainbow trout)): 54,000 mg/l
`Exposure time: 96 h
`
`: EC50 (Daphnia magna (Water flea)): 1,955 mg/l
`Exposure time: 48 h
`
`: NOEC (Pseudomonas putida): > 10,000 mg/l
`Exposure time: 16 h
`
`
`Octamethylcyclotetrasiloxane:
`
`Toxicity to fish
`
`
`Toxicity to daphnia and other
`aquatic invertebrates
`
`
`Toxicity to algae
`
`
`Toxicity to fish (Chronic tox-
`icity)
`
`
`Toxicity to daphnia and other
`aquatic invertebrates (Chron-
`ic toxicity)
`
`
`Ecotoxicology Assessment
`
`: LC50 (Cyprinodon variegatus (sheepshead minnow)): >
`0.0063 mg/l
`Exposure time: 336 h
`Remarks: No toxicity at the limit of solubility.
`
`: EC50 (Mysidopsis bahia (opossum shrimp)): > 0.0091 mg/l
`Exposure time: 96 h
`Remarks: No toxicity at the limit of solubility.
`
`: ErC50 (Pseudokirchneriella subcapitata (green algae)): >
`0.022 mg/l
`Exposure time: 72 h
`Remarks: No toxicity at the limit of solubility.
`
`: NOEC (Oncorhynchus mykiss (rainbow trout)): >= 0.0044 mg/l
`Remarks: On basis of test data.
`No toxicity at the limit of solubility.
`
`: NOEC (Daphnia magna (Water flea)): >= 0.0079 mg/l
`Exposure time: 21 d
`Remarks: On basis of test data.
`No toxicity at the limit of solubility.
`
`
`Chronic aquatic toxicity
`
`
`: May cause long lasting harmful effects to aquatic life.
`
`
`15 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 15 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`Persistence and degradability
`
`Ingredients:
`
`Glycerine:
`
`Biodegradability
`
`
`: Result: Readily biodegradable.
`Biodegradation: 94 %
`Exposure time: 1 d
`
`
`Octamethylcyclotetrasiloxane:
`
`Biodegradability
`
`
`Stability in water
`
`
`: Result: Not readily biodegradable.
`Biodegradation: 3.7 %
`Exposure time: 28 d
`Method: OECD Test Guideline 310
`
`: Degradation half life: 69.3 - 144 h (24.6 °C) pH: 7
`Method: OECD Test Guideline 111
`
`
`Bioaccumulative potential
`
`Ingredients:
`
`Glycerine:
`
`Partition coefficient: n-
`octanol/water
`
`
`:
`
`log Pow: -1.76
`
`
`Octamethylcyclotetrasiloxane:
`
`: Species: Pimephales promelas (fathead minnow)
`Bioconcentration factor (BCF): 12,400
`
`log Pow: 6.48 (25.1 °C)
`
`
`:
`
`Bioaccumulation
`
`
`Partition coefficient: n-
`octanol/water
`
`
`Mobility in soil
`
`No data available
`
`Other adverse effects
`
`Ingredients:
`
`Octamethylcyclotetrasiloxane:
`
`Results of PBT and vPvB
`assessment
`
`
`: Remarks: Octamethylcyclotetrasiloxane (D4) meets the cur-
`rent REACh Annex XIII criteria for PBT and vPvB. In Canada,
`D4 has been assessed and deemed to meet the PiT criteria.
`However, D4 does not behave similarly to known PBT/vPvB
`substances. The weight of scientific evidence from field stud-
`ies shows that D4 is not biomagnifying in aquatic and terres-
`trial food webs. D4 in air will degrade by reaction with naturally
`occurring hydroxyl radicals in the atmosphere. Any D4 in air
`that does not degrade by reaction with hydroxyl radicals is not
`expected to deposit from the air to water, to land, or to living
`organisms.
`
`16 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 16 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`
`
`SECTION 13. DISPOSAL CONSIDERATIONS
`
`Disposal methods
`
`Resource Conservation and
`Recovery Act (RCRA)
`
`Waste from residues
`
`Contaminated packaging
`
`: This product has been evaluated for RCRA characteristics
`and does not meet the criteria of hazardous waste if discarded
`in its purchased form.
`
`: Dispose of in accordance with local regulations.
`
`: Empty containers should be taken to an approved waste
`handling site for recycling or disposal.
`If not otherwise specified: Dispose of as unused product.
`
`
`SECTION 14. TRANSPORT INFORMATION
`
`International Regulations
`
`UNRTDG
`
`Not regulated as a dangerous good
`
`IATA-DGR
`
`Not regulated as a dangerous good
`
`IMDG-Code
`
`Not regulated as a dangerous good
`
`Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
`
`Not applicable for product as supplied.
`
`Domestic regulation
`
`49 CFR
`
`Not regulated as a dangerous good
`
`SECTION 15. REGULATORY INFORMATION
`
`EPCRA - Emergency Planning and Community Right-to-Know
`
`CERCLA Reportable Quantity
`
`This material does not contain any components with a CERCLA RQ.
`
`SARA 304 Extremely Hazardous Substances Reportable Quantity
`
`This material does not contain any components with a section 304 EHS RQ.
`
`SARA 302 Extremely Hazardous Substances Threshold Planning Quantity
`
`This material does not contain any components with a section 302 EHS TPQ.
`
`SARA 311/312 Hazards
`
`
`: Reproductive toxicity
`
`
`17 / 20
`
`Brooks Sports
`Exhibit 1078
`Page 17 of 20
`
`

`

`SAFETY DATA SHEET
`
`DOW CORNING(R) 3179 DILATANT
`COMPOUND
`
`
`
`
`
`
`Version
`5.0
`
`Revision Date:
`09/14/2017
`
`SDS Number:
`1019537-00008
`
`Date of last issue: 03/09/2017
`Date of first issue: 12/22/2014
`
`
`
`SARA 313
`
`
`: This material does not contain any chemical components with
`known CAS numbers that exceed the threshold (De Minimis)
`reporting levels established by SARA Title III, Section 313.
`
`
`US State Regulations
`
`Pennsylvania Right To Know
`
`
`
`
`
`
`
`
`
`
`Dimethyl siloxane, hydroxy-terminated polymers with boric
`acid
`Quartz
`Castor oil derivative
`Dimethyl siloxane, trimethylsiloxy-terminated
`Titanium dioxide
`Glycerine
`Aluminum oxide
`
`104780-67-8
`
`14808-60-7
`Not Assigned
`63148-62-9
`13463-67-7
`56-81-5
`1344-28-1
`
`California Prop. 65
`
`This product does not contain any chemicals known to the State of California to cause cancer,
`birth, or any other reproductive defects.
`
`California Permissible Exposure Limits for Chemical Contaminants
`
`
`
`
`
`Quartz
`Titanium dioxide
`Glycerine
`
`California Regulated Carcinogens
`
`
`
`Quartz
`
`14808-60-7
`13463-67-7
`56-81-5
`
`14808-60-7
`
`The ingredients of this product are reported in the following inventories:
`
`NZIoC
`
`REACH
`
`
`TSCA
`
`
`AICS
`
`IECSC
`
`ENCS/ISHL
`
`
`KECI
`
`PICCS
`
`DSL
`
`: All ingredients listed or exempt.
`
`: For purchases from Dow Corning EU legal entities, all
`ingredients are currently pre/registered or exempt under
`REACH. Please refer to section 1 for recommended uses. For
`purchases from non-EU Dow Corning legal entities with the
`intention to export into EEA please contact your DC
`representative/local office.
`
`: All chemical substances in this product are either listed on the
`TSCA Inventory or are in compliance with a TSCA Inventory
`exemption.
`
`: All ingredients listed or exempt.
`
`: All ingredients listed or exempt.
`
`: All components are listed on ENCS/ISHL or exempted from
`inventory listing.
`
`: All ingredients listed, exempt or notified.
`
`: All ingredients listed or exempt.
`
`: This product contains one or more substances which are not
`
`18 / 20
`
`Brooks Sports
`Ex