4/2/2018
`
`http://www.crouse-hinds.com:80/CrouseHinds/resources/msds/Msds_isocyanate.cfm
`
`7 captures
`23 Dec 2003 - 26 Oct 2006
`
`TTTTTTTTEEEEEECCCCCCHHHNNNIIIIIICCCAAAAAALLLLLLLL RRRRRREEESSSOOOOOOUUUUUURRRCCCCCCEEEEEESSS
`TECHNICAL RESOURCES
`
`Isocyanate | Material Safety Data Sheets | Technical Resources | Cooper Crouse-Hinds
`Go APR JUN MAR
`26
`
`2003 2004 2006
`
`
`
`(cid:66) ⍰ ❎
`
`
`f (cid:64)
`
`▾ About this capture
`
`
`
` PRINT
`
`COOPER INDUSTRIES/CROUSE-HINDS DIVISION: ISOCYANATE
`
`MATERIAL SAFETY DATA SHEET
`
`PRODUCT AND COMPANY IDENTIFICATION
`
`COMMON NAME:
`
`Diphenylmethane diisocyanate
`
`CHEMICAL FAMILY:
`
`Aromatic Isocyanate
`
`FORMULA:
`
`Mixture
`
`PRODUCT CAS NO.:
`
`101-68-8 (Methylene bisphenyl isocyanate, MDI)
`
`SUPPLIER:
`
`ADDRESS:
`
`Cooper Industries/Crouse-Hinds Division
`
`P.O. Box 4999
`
`CITY, STATE, ZIP:
`
`Syracuse, NY 13221-4999
`
`PHONE:
`
`(315) 477-7000 Emergency Phone: 1-800-424-9300 CHEMTREC
`
`INGREDIENTS: COMPOSITION/INFORMATION
`
`INGREDIENT
`
`% WEIGHT
`
`PEL-OSHA
`
`TLV-ACGIH
`
`LD50/LC50
`
`ROUTE/SPECIES
`
`Diphenylmethane diisocyanate or
`Methylene bisphenyl Isocyanate (MDI)
`
`60-100
`
`0.02 ppm
`(Ceiling)
`
`0.005 ppm
`
`LC50:369 mg/m3 (4 H)
`(inhalation/male rat)
`
`CAS Number: 101-68-8
`
`
`
`
`
`
`
`HAZARD IDENTIFICATION
`
`POTENTIAL HEALTH EFFECTS
`
`NOTE: When reacted, this product is a portion of a 2-part rigid polyurethane foam. MDI and polyol are supplied in separate
`plastic compartments in a closed plastic container. The barrier between the two substances is broken before dispersion.
`Contact with unreacted MDI is not expected under normal working conditions.
`
`
`EYES: May cause irritation and redness.
`
`SKIN: May cause irritation and sensitization.
`
`
`INHALATION: Toxic if inhaled. May cause irritation or sensitize the respiratory tract. Sensitization of the respiratory tract may
`cause asthma attacks with chest tightness, breathlessness and discomfort.
`
`http://web.archive.org/web/20040626191108/http://www.crouse-hinds.com:80/CrouseHinds/resources/msds/Msds_isocyanate.cfm
`
`1/5
`
`Cooper Ex. 1011
`
`

`

`4/2/2018
`
`
`Isocyanate | Material Safety Data Sheets | Technical Resources | Cooper Crouse-Hinds
`
`
`SIGNS AND SYMPTOMS: Inhalation may cause burning of the nose and throat, cough, laryngitis, chest pain andSSIIGGGGNNSSSS AANNNNDD SSSSYYMMMMPPTTTTOOMMMMSS:: IInnhhaaaallaattttiioonn mmaayy ccaaaauusseeee bbuuuurrnniinngg ooooff tthhhhee nnnnoosseeee aannnndd tthhhhrrooaaaatt, ccccoouugggghh, llllaarryyyynnggiittttiiss, cccchheeeesstt ppppaaiinn aanndddd
`asthmatic symptoms. May cause eye and respiratory irritation. Skin and respiratory sensitizer.
`asthhmaatic syymmpptoomss. Mayy ccausse eeyye andd resppirratoryy irrritaationn. Skkin aandd ressppiraatorryy seensitizeer.
`
`CHRONIC: None known.
`
`CARCINOGENICITY:
`
`IARC: No
`
`NTP: No
`
`OSHA: No
`
`MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: May aggravate pre-existing respiratory conditions. Individual with
`asthma or other respiratory conditions should not be exposed to this product.
`
`TARGET ORGANS: Lungs, eyes, skin
`
`FIRST AID MEASURES
`
`EYE CONTACT: Flush eyes with lukewarm water for at least 15 minutes. If irritation persists, get medical attention.
`
`SKIN CONTACT: Remove contaminated clothing and wash skin thoroughly with soap and water. If irritation develops, seek
`medical attention.
`
`INHALATION: Remove to fresh air and give oxygen or artificial respiration as indicated. Get immediate medical attention.
`Individuals that become sensitized to this product should avoid further exposure to prevent serious allergic reactions.
`
`OTHER: DO NOT INDUCE VOMITING. Give 4-8 ounces of milk or water and immediately call a poison control center or a
`physician. Never give anything by mouth to anyone that is or could rapidly become unconscious.
`
`FIRE FIGHTING MEASURES
`
`FLAMMABLE PROPERTIES
`
`FLASH POINT: 221  C (430  F)
`
`ASTM D-93, Closed Cup
`
`
`
`NFPA HAZARD CLASSIFICATION:
`
`HEALTH: 3
`
`FLAMMABILITY: 1
`
`INSTABILITY: 1
`
`FLAMMABLE LIMITS:
`
`LEL: Not Applicable
`
`UEL: Not Applicable
`
`EXTINGUISHING MEDIA: Water fog, foam, dry chemical, or carbon dioxide.
`
`FIRE AND EXPLOSION HAZARDS: Non-flammable. Water contamination produces carbon dioxide gas. This may cause
`pressurization or explosion of containers.
`
`FIRE FIGHTING EQUIPMENT: Firefighters should wear a NIOSH/MSHA-approved, full-facepiece self-contained breathing
`apparatus (SCBA) operated in positive pressure mode and full turnout gear with additional chemical protective clothing as
`necessary to prevent exposure to hazardous decomposition products.
`
`
`
`
`
`
`
`ACCIDENTAL RELEASE MEASURES
`ACACCICIDEDENTNTALALTT
`RERELELEASASEE MEMEASASURURESES
`http://web.archive.org/web/20040626191108/http://www.crouse-hinds.com:80/CrouseHinds/resources/msds/Msds_isocyanate.cfm
`
`2/5
`
`Cooper Ex. 1011
`
`

`

`4/2/2018
`
`Isocyanate | Material Safety Data Sheets | Technical Resources | Cooper Crouse-Hinds
`
`
`ACCIDENTAL RELEASE MEASURESACCIDENTAL RELEASE MEASURESTT
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`b t t i l dd l itiit bblithhillbllitill dhlkk thtff illtlIIsolate areea off spill. DDDDo nnot wwalkk thrrouggh sspilleed mmateeriall. AbbAbbsorrb spill wwithh suitabble innert sorrbennt mmaterial andd plaace in oopenn
`Isolate area of spill. Do not walk through spilled material. Absorb spill with suitable inert sorbent material and place in open
`
`coconntntnt iaiainnnenerr IfIfIf uunnnmnmiixixxx deded MMMDDDDIDIDI iiiss spspiiillllleleddd uusssese aapppproroooprpriiiaattete ccononnnttrtr lolollll mmeeeaeasusuuureressss ananddd lplplacaceeee iinin ttttttiigighhhtttllyly ccccllolosseeddd cccoco tntntttt iaiainneerr aafafaftteterrrr bababsssoso brbrbbbbiiningggg
`container. If unmixed MDI is spilled, use appropriate control measures and place in tightly closed container after absorbing
`with inert sorbent. Thoroughly clean area of spill to prevent slipping. Wear protective clothing appropriate for the level of
`exposure. Decomtaminate absorbent and spill area with a solution of 90% water, 8% ammonia and 2% detergent.
`
`
`
`
`
`
`
`
`
`HANDLING AND STORAGE
`
`Store in a cool, dry, well-ventilated area. Do not open cans or outer foil bag until ready to use. Avoid contact with skin, eyes,
`and clothing. Do not breathe vapors or mists. Promptly remove contaminated clothing promptly and launder separately.
`Wear clean work clothes daily. Wash thoroughly after handling and before meals, breaks, and smoking. Do not eat, drink, or
`smoke in work and storage areas. Do not store food, cosmetics, cigarettes or other personal items in storage and use areas.
`Use only in well ventilated areas.
`
`EXPOSURE CONTROLS/PERSONAL PROTECTION
`
`RESPIRATORY PROTECTION: Under normal working conditions below acceptable exposure guidelines, none required.
`For concentrations above acceptable exposure limits, wear NIOSH approved respiratory protection in accordance with
`OSHA 29 CFR 1910.134.
`
`SKIN PROTECTION: Polyvinyl or rubber gloves and coveralls.
`
`EYE PROTECTION: Wear chemical goggles or full facepiece respirator according to levels of exposure
`
`ENGINEERING CONTROLS: Local exhaust ventilation used in combination with general ventilation as necessary to
`control air contaminants below acceptable exposure guidelines.
`
`PHYSICAL AND CHEMICAL PROPERTIES
`
`APPEARANCE:
`
`Dark brown liquid
`
`ODOR:
`
`MELTING POINT:
`
`SOLUBILITY IN WATER:
`
`SPECIFIC GRAVITY:
`
`Odorless
`
`N/E
`
`Insoluble
`
`1.2 g/ml
`
`BOILING POINT:
`
`200  C (392  F)
`
`VAPOR PRESSURE:
`
`0.00016 mm Hg (@ 25  C)
`
`STABILITY AND REACTIVITY
`
`STABILITY: Stable.
`
`INCOMPATIBILITY: Reacts with strong alkalis, acids, alcohols, and oxidizers, water or moisture and temperatures above
`300  F. Reaction with alcohols can be violent. MDI polymerizes at 450  F.
`
`HAZARDOUS POLYMERIZATION: Will not occur.
`
`http://web.archive.org/web/20040626191108/http://www.crouse-hinds.com:80/CrouseHinds/resources/msds/Msds_isocyanate.cfm
`
`3/5
`
`Cooper Ex. 1011
`
`

`

`4/2/2018
`
`Isocyanate | Material Safety Data Sheets | Technical Resources | Cooper Crouse-Hinds
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`
`DISPOSAL CONSIDERATIONSDISPOSAL CONSIDERATIONSAA
`
`Recycle, reclaim and dispose of in accordance with applicable local, state and federal regulations. Dispose per 40 CFR Part
`261 and 262.
`
`Not regulated
`
`TRANSPORT INFORMATION
`
`REGULATORY INFORMATION
`
`WHMIS CLASSIFICATION: D1A,, D2A, D2B
`
`OSHA Regulatory Status (29 CFR 1910.1200): This material is classified as hazardous under OSHA regulations.
`
`SARA TITLE III - SECTION 313 SUPPLIER NOTIFICATION:
`
`This product contains the following chemicals subject to the reporting requirements of section 313 of the Emergency
`Planning and Community Right-To-Know Act (EPCRA) of 1986 and 40 CFR 372:
`
`Chemical
`
`MDI
`
`CAS Number:
`
`101-68-8
`
`% Weight
`
`60-100
`
`California Proposition 65: This product does not contain ingredients known to the State of California to cause cancer, birth
`defects, or other reproductive harm.
`
`OTHER INFORMATION
`
`ACGIH: American Conference of Governmental Industrial Hygienists
`
`IARC: International Agency for Research on Cancer
`
`NIOSH: National Institute for Occupational Safety and Health
`
`NTP: National Toxicology Program
`
`MSHA: Mine Safety and Health Administration
`
`OSHA: Occupational Safety and Health Administration
`
`TLV: Threshold Limit Value
`
`PEL: Permissible Exposure Limit
`
`The information in this MATERIAL SAFETY DATA SHEET should be provided to all who will use, handle, store, transport,
`or otherwise be exposed to this material. This information has been prepared for the guidance of plant engineering,
`operations and management, and for persons working with or handling this material. Cooper Industries/ Crouse-Hinds
`
`http://web.archive.org/web/20040626191108/http://www.crouse-hinds.com:80/CrouseHinds/resources/msds/Msds_isocyanate.cfm
`
`4/5
`
`DISCLAIMER
`
`Cooper Ex. 1011
`
`

`

`Isocyanate | Material Safety Data Sheets | Technical Resources | Cooper Crouse-Hinds
`4/2/2018
`Division believes this information to be reliable and up-to-date as of the date of publication, but makes no warranty that it
`Division believes this information to be reliable and up-to-date as of the date of publication, but makes no warranty that it
`is.
`is.
`
`
`
`Revision Date: 4/10/03
`
`
`
`Cooper Crouse-Hinds
`
`
`P.O. Box 4999
`
`Syracuse, NY 13221-4999
`
`
`
`
`
`
`
`Phone: 315.477.5440
`
`Fax: 315.477.5179
`
`http://www.crouse-hinds.com
`
`http://web.archive.org/web/20040626191108/http://www.crouse-hinds.com:80/CrouseHinds/resources/msds/Msds_isocyanate.cfm
`
`5/5
`
`Cooper Ex. 1011
`
`