JP 20127183031 A 2012.53.27
`
`(19) EIIFIfiE’FFfiJP)
`
`(12) ’13 I35 31% E‘F {I}: iluA)
`
`(51) lnt.C1.
`C13K T/EE WIN)
`COZF
`174$
`(313.01)
`3010 51/44 m.01)
`3010 61/46
`(2006.01)
`
`F1
`
`C13K 1/02
`CO2F
`1/46
`BOlD 81/44
`BOlD 61/46
`
`103
`500
`
`(43) ME El
`
`(infiéfiififififififi
`44552012433031
`(mom—13303111)
`51213245951er (2012.9. 21)
`
`(33%)
`
`?—?:—l€
`4D006
`4D061
`
`
`
`
`
`fiifilfitbfl 9 0LEfiéfifli ififiifi (fi 13 E)
`
`@Dmflfi%
`@fimflfi
`
`fimmu4m%emu4M%)
`Wmfi$fifififlm133
`
`UDHEA mmmm4
`mfifilfififiéfi
`fiEEWJfiFfimaEIZEJIIm-fim 3TB 1 E 1
`%
`Uflfifik HWW%6
`fifififiEA fiafifigfim
`Umfififi fi$ $
`fififimfifimfiflfiNWMSTfilfil
`% MflélfififléfiWfilfim
`Umfimfi WE gm
`EEEWfifi¢%E§MWm3TEIE1
`% mfifilfififiéfimfilfim
`Umfifi? mfi mi
`fiEEfiEfiMWEIEIfi MWEI$
`fifiéfimfilfim
`fifigfiiififi
`
`(54)
`
`1%513033331 fifiifififi‘fifitfififiififififi
`
`(57)
`
`[E141]
`
`[fir‘fi] figfiflfififlfi'fié’s fifiitififib‘ Béj‘filllfillll‘é” Z> f:
`bflfifififififii 313%034: 5 fififiififififlifi$fifi
`
`1: (EH? ‘6 41%) EE'EfiiEfié-Efiéfiffifi % C 3: o
`
`[fiflpflififil Zlfifififi 'Cmtx fififii‘fifigém b ‘11:ij
`
`— X}?! */f $7X®Efififtfi§b B¥E§ifiifi®fiEEfiHU L
`
`“C EUR?" Z: a $fii§$fi%§ 1C 5: ‘
`
`119314371? 21%;}??? 2: 751%
`
`H 13 21125 ‘3 \ ififiiflx @4221. Vfiflfifibai 9 "GEE
`
`1E'1®%#1%fi§§ E: @Efiflahfiififififi 2: avian é hfh \
`
`25 c. Hfiifiiiz 12L 131335111951 tfifilfilfllfiflfififififiéhffi ‘9
`
`\ fiégfifigédi‘ fifiifl®fi1bifi1ififiéh% 1&0)
`
`[524’ 71 Vfiifiaflitiifi‘é fiiflififimffiib ‘15:me
`'3 15‘
`3‘70”) fi—‘EfililflRfiflgb‘Efi-é inf—4’6 ‘0 \ fi:¥§¥ffi§1c bi
`
`\ @If 21‘ Vfifiéfil: SET? éifififigwifiwfié‘lfilflflfi F59
`
`%7%EWfi%h‘fifié fl‘C’L \E) o
`
`[ERIE]
`
`1
`
`
`
`

`

`(2)
`
`JP 20127183031 A 2012.9.27
`
`[fighfigfiificDfifilfil]
`
`[fifliffill
`
`Eifificszfififiifiba *EfiifiifimflEfi‘BULTIEIHETZéfiET-‘Efiuf\
`
`fififiEH‘EfiMEfiECDECi‘ [Kg/1’71Vfififlfibifirfijéifiifliifib‘flfié%#®%&fi%:®%
`
`Efigfix
`fififiafiédDMUDE/fZ’Vfifiéflfiffifi?‘%ifiifli§§b\ fifi?€%:®&®fi§4’t‘/§Efiafiic
`
`ififiéfiififilfiib1LEWCE7‘i’fiflffiL/T‘ fifiéflflfifififibififiéhéfifiéflfi:®fléfi#
`
`BIKE/{71'Vfififlfimffifi‘lflflb‘8%fljfiflflifiifléfi’éfigifiifllfia‘
`
`fifififlfié‘:®fl7&\ fifiéfii’fié‘DEIffl'Vfifiéflfi0)fi%fififlilffififié?fi:wfi4iVfimflfi
`
`@fiéiffiififlfi‘6%@wfi3§3fléfiéttibia. fififiafiifiékfifibzfifiéhéfifififlfi#®%%fifi
`
`§E%#®K%4tyfiififlfi®flfiffiffiflfiBEEEEHAEEEE'Efiififiifi-t\
`
`%fi’?%tt%¢$f¥téfi?%fjffio
`[fiflilfizl
`
`fifififlfig®flfififififlfiéfibx W§E%:®@hififlfiflfii‘6%‘ EEfliIEIPCEEfiWDHEEO
`[fiéfififiB]
`
`fifififlfififla‘fii’fifi‘
`
`tibu—X%I§%172®%fi1tfi§'fifi%\ fififilfifliZbafiflfitD
`
`EEO
`
`[fififlilfitl]
`
`WEEfiéDfix W33$Z®fikt§fifi§flfig®fitfifiéflfi:®fi€h‘fi%£éhtfi$flz$fié
`
`Ifilfllfélfilflfllfiéfifi‘éfi‘ fifiifilflismmfhb‘ 1 IfibzéfliEGDfiiio
`[fiififiS]
`
`EWEflTcfifiéflfifiiCDME“ 1211/D—Xf—fEN/f£72®E§fifljifiiififlffifié\
`
`£1: j?
`
`EIPJEAIODU‘fth‘llfiLCEEiEODfii/fio
`
`[Egflilfib‘]
`
`JCJbD—236111/f'iVXUDEQfifEMEEWiCfiEéfléfifififig/f71‘Vfifiéfléilfi‘fi‘zfifi
`
`fififib‘fifi%¥§§ifi¥fi®fl&fififlLTEW?%?¢®®%§EE%E'G&331\
`
`fifi?fl%fi3§1fi%§6i\
`Hfiifiikififififikflffiix
`
`fifififlflfiifificlcix HfififiitifiEWEEfifififiéhTfi0\
`
`fifiéafgfifiici\ Elfjyfifiafiél—TLL‘ODFHWCEfi‘Z)fiéhfififl®%#fiéffifi§tfi§flfifl®%:
`
`igfifiitv‘i’fififii‘
`
`fififiafiéfififificici\
`
`fifiéfl%:®%&c}:0PE»fifiéflfififii‘yfifififibCHfi'%fiiflifigwflib‘
`
`fififififi—QE’éEW'fi‘Efifi—Mfilflififlfififfifiéhffo‘D\
`
`fifiéflfi:i§$fi§bici\ fifiéflfigQMiO ’Efifiéflffi/I’i‘yfifiafiifififi’é’ofiififigdfiélw
`
`W§E$:®MEEW?%$ZMEWEE§#EfiEa‘lTanE)E:£32¢$f£1£f%‘ Efifififi
`E0
`
`[fifliIEYJ
`
`{ZJDDHX%J§/(fi’?7x®%$§ftflflifibigfiéflgfifififlg’ffl‘Vfifiéfiilifi'fi—éifi
`
`Eflgfi‘fifi%¥fififiifi®fi?&fiwbflfilflifi‘%fc&b®€-§§ii§$fi%§%'éfiof\
`
`W§E$fifiifiififlfifici-, K2471Vfififlfibififi‘éfifiifififififi:6%#®%EU‘%:®E
`
`Efi‘guh
`
`fifiéflfifiififiifififix
`
`Hfiifiiaifififiia&fiix
`
`"fifififlflfiifificzx‘ @EEULCKEIffi‘VfiflHfifiéfib‘ WON fifi$ftfi§lfllflkfifififififiéh
`(339‘
`
`fifiiflgfifiifli‘ @fljfiflbCfifi’ffi‘Vfiifilfi/fih @E‘iflflliflfitffl‘yfimfiifjfihjfhfibx
`
`yb\')\
`
`[524’d‘VfiJfiHQEEWODFEEHCfi—d'é@Efiflwfiéifififitfi%fififfifl®%:ifififfi§t%
`
`{Eix
`
`fifi?€%#i§$fi$bici\
`
`fifiéflfi:®fi€$0 Efififiafi24’iVfiEfifiiiCfi‘é’%Eifiifl§l§®ffliw
`
`fififififi—Qflfiffilfllfi‘fifi—Mfilfllfiflfififfifiéhfh"9w
`
`10
`
`20
`
`30
`
`40
`
`50
`
`

`

`(3)
`
`JP 20127183031 A 2012.9.27
`
`fi%%:%%$wm\m%%—®m;0%fi%@4tv§mfiwfiiéfiflfifiwfiw
`
`fi%%:®m&fiflia%:wfiflfififififiéhffiD\
`
`mfimfi§W®fififlfimfi&WEMEt%afim\WEE—@EW%%&6WE%:
`
`fififlfififlgxmfifiéwflkGfiE%:®%%%h%hEW?éza%%fit?6\
`
`fififimfifio
`[fififia]
`
`WfiflfiiQEfiWE$4iyfififiEfi?é\fififi7fififi®fifififififiu
`
`[Ea-flimsy]
`
`fififlEékafififififififiufififiw5h1m%\%fifi6fi§smm€hv1
`fiafifi0fifififi§fio
`[fifiwfiflfififi]
`
`[fimfifi]
`
`m001]
`
`$%%H\fi§fiwffi¢u—Z%N4$7ZEfikflfiLE$fl%T%5%%kflfi
`fi®$5fififififingfififiQfl§$fififiEK$offl%EW?§fiE\&3%®
`
`:5fififlflmwkbwafififififiufimfié$fififi%§tfifiéo
`
`[fifififi]
`
`[000m
`
`Nfifivxlfiwfi—flEQ—fitLT\EWQEfififiEfitWU—Zxfifiitw
`
`u—Xfififiiflm I?/~—)l/ (zfirrzi'IérJ—Jlx) 381%;5tkfi‘ééfifii7b‘aazéa @13th
`
`I?/—»@\Mflmtbritbfaflfimflmgflfixéfitb\fiVUywfififi
`
`Habfflmfihkbfi%zafififiémrmég
`[000M
`
`EW®$tfifim\twu—X\Aitwu—z‘Ufi:y2@%yfyfi@ém\l
`
`é/~Wflfi»u~X%fi%LT%Bfl%5Wu—X\AEtWU—X%fiflbffi6h
`
`§$VU—2\fifi%h5®fifififi5éiUflfi§®fifiéfiflth\fififiw$5
`
`fifiiflamfifimwiofifién%o
`
`[000M
`
`10
`
`20
`
`hwu—XxflfiitWU—Z®$5&tWU—X%fiffivxéfifinfififi%Kd
`\UVfilflfifl®$5fifl®flkfifi$bmmfiflf%fifi(fimmfififi)fiéfifi
`
`30
`
`EflmémfwaoCQEWKfifiETu\%MLE@#%EE®WfiEfiLTm%%E
`
`£fiazab6\tmu—XRMAEtwu~X%%fiwfiflbkfi\fimfitfifiéh
`
`éfifiE1§/—w%fiéfi%fiE\ME%£RM¢W?%%EW%%D
`
`{000m
`
`%%Ifi1u‘fifim&mfimefiMLTfimfi$WL\$flbtfi§&flfifi%fi
`
`%C&M$of\fimfi$®fifl%%£?éfifi%fifibfméoCCT\%kfi#B%
`
`mbfififlififlfiéhflx¢m®hb®figfi$fitfibxjxfi&mfiféi£fim
`fiE‘ctzgyifi‘ ¢%%’F§Ci’flfltcfififiéflfh\%fiifi'flah EEb‘Bfififi%fi$fi'%Eafiil¥fi
`
`'C~‘%Zao
`
`[000m
`
`#fixfififim2@\mfimfi%4fiy§&fi%ufib\fifl&fi%&6wfl¢%fim
`%%fibfm%oikxfifififiauxtmn—X%m4ivx&fifikMEfiézam
`ioffifi - flaififififiéflififzafififtlfi‘t‘ fimfimlfibfjfighlEfl-fiflfiiflva
`
`\@4%V§&fi%mmafiflfifi%u;o50tfl?®fi§fifififlfl%fioffltfi
`fi%fi%?5fififlflTEt%fifl5iE%%fl£¢&\tWU—Z%N%i?2#6%
`
`fi%flfi?éfi%%fiibfw50fifiimBEfifiéhfméfiEfi\{iyfimfiE
`
`MWTEGHW&UfiWWEW%8L‘7Ut2$¢®1$$£~32¥fl3$fififié
`
`flfi?%CEEEM&LTW%O
`
`[fifififififi]
`
`[fifififi]
`
`40
`
`50
`
`

`

`(4)
`
`JP 20127183031 A 2012.9.27
`
`[000M
`
`[%%imll%%2006—75007%flfi
`
`[fifiifizlfifi2005740106%£fi
`
`[fififimslfifizoog—zzlaogfifi
`
`[%%®mfil
`[fifififimb$58?%fifil
`
`[000M
`
`fimfi¢mu\twu—XRMAEtWU—x0%mfim®m$fl%?%éfififi(E
`
`fl)fifiEEhTW%D%kIET%m?%%%fifl\%%E\#O\%M?%éh®\
`
`fififl%fikfifi6@flbwUfidfimvézafifiibmoLbb‘fimfi¢mmxfi
`
`fimkfifififlfififibfw%hb\fifimfiflfibfifififl&fimlfifififlflfi%a
`
`\fimIE0fififlfifififimb\fit:fimfi%§%&fi?m\fiEWJXbfitfifi
`égflmfifib\EBEQ‘EWL€hfi<fiotEfififi\@flmfifilfimfiwffi
`
`fi%fl§¢%aw5fi%fifi%oto
`[000m
`
`#fi\%%ifiafifiswfi%énfm%fifififi\fimfi¢tfifiéhfm%fififi
`
`fi®fléfiflbffiflfiéztflr§tmo
`
`[001m
`
`$%%H~tWDHX%N%$?X%fi%@K$a?%kflflbfi$fi%fi%é%%m
`
`fi#6\fififififififiQméfiWEflf%hbfififififififi\&3%®$5fi%fifi
`fifififlifitfifléh6§fififi£fi®%fiéEmtfiéo
`
`[fifiéflfifiékb0iE]
`
`[001M
`
`$%%%%u\M%mfim;5nflfififibBEfiEmflEfiwMW?%fi%mowf
`
`3fi%&%bko%®%%1flfiitfifiétW§thfbéfifififigfihfibfx
`
`E41V§fififi$offifi$éfi%b\mafiafifléhkfifiiam%h?hfifib
`
`kfimfifi(fi%fi%)%%Hffimm%mfi¢hfi‘@fiiyfimfiufifiéfififia
`
`fifiwmflfi6@fififl®fl&fifibfflfififififlflfifi£éCEEEHL\$%W&
`
`fififiéfi‘zbéfiliofco
`[001m
`
`Ewmm‘$%%m\
`
`fifififimgbflfififib5\fifififi®%%fifiLTEW1éfiafi%af\
`
`fifififififimflm\fififiyfififiwfi¢%fififififififi%%—®M&fi%:®fi
`
`éfiax
`
`%%$—®%®@%1V§mfiwfliéfififififi‘WE%:®%®@diyfimfiw
`fi?&fiflfi§$bfimiaéflmbT\fififififififififiéhéfififi:®flé%#
`
`QfififiVfififiQEEWWBfififlmfifiéfiéfi#fifilfia\
`
`fia%:®%E\%fi%#®@%tyififiw§fiflmmfité%:®@%iyfififi
`
`Qfifififl5@EWEEfiéfiéaa%w\Wfififikfiwafiéh%fififiéwfi&fi
`
`fifi—fifidiy§&EQEEWW6%mmafifiéfié%:fifilfit\
`
`Efiféctéfifltféfiflfi%fiéo
`
`m013]
`
`Wfifié®flfifififlfifibxWfifi:®flfiflfififi§élafi%ibwo
`
`[001M
`
`W§Mfifififi\tNU—XfifixivxmfifikfiT55Ctfifiitwo
`[0015]
`
`$fifl®fi%@\%$%#®%\%E%:®%&U%%%#®%t%%%:mfifififi
`
`éhkfifimfi%fiflfiéEWTfi&fifiécafifiibwo
`
`[0016]
`
`Eflémkfififi:®mfi‘twu—X%N4ivxmflfimlfimfiflméh%:&
`
`10
`
`20
`
`30
`
`40
`
`50
`
`

`

`(5)
`
`JP 2012483031 A 2012.9.27
`
`EEK Luv,
`
`[001H
`
`jigfiflfifli ift\
`
`EEDHXEH4fivszEmEEEMEEEhéEEGEdiVEEEKEEEE
`
`EEEEEEEEEEEGEEEELTEEEEKEQEEEEEETEof
`EEEEEEEEE‘
`
`EEEKEEEKEEZ\
`
`EEEEEEE\EEEEEEEEEEEEEEYED‘
`
`EEEEEE\E4?VEEEEEVQEKEEEEEEmEEEEEaEEEwE:
`
`EEEtEEE
`
`EEEE EEEEE\EEE: mEngEEEfEVEEEEEEEEEEEQEV
`
`EEEE @EEEEEEEE EEEEEEEEEECED
`EEE: EEEEE\EEEE @EEOEEEEKEVEEEEEEEEEEEQEW
`
`EEE: @EEEEEEE: EEEEEEEEEETVECaEEEEEE‘EEEEE
`
`E(EE @EEEEE*E)EEE%O
`
`[001M
`
`EEEM Eitx
`
`EEG—XENJEVKQEEEEEEEEEEEEEEEE4EVEEEEEEEE
`
`EEEEEEEEEEEwEEEELTEEEEEE®EEEEE ETEGT
`
`EEEEEE®EE‘EKEVEEEKEEEEEEEEEEEEE @EEUE:®E
`EEE
`
`HUEEEEEEEEG:
`
`EEEEEEEEEEE\
`
`10
`
`20
`
`EEEEEE\EEEKE%EVEEEEEL\#9\EEEEEEEEEEEEEE
`130‘
`
`EEEEEE EEEKEKEVEEEE EEEKEJEVEEEEEEEEEL
`
`fiflxEXEVEEEEEWQEEEEEEEWQEEEEEEEEMQEZEEEEE
`Eix
`
`EEEEEEEEE\EEE:®EEOEEEEEEVEEEEEEEEEEEmfiw
`WfifiEQMEEW?5%E@EW§%fi%fiEhffiDx
`
`30
`
`EEE:EEEME\EEE-®EEOEEEEEEVEEEEEEEEEEEme
`
`EEE:®EEEEEEE:EEEEEEEEEETED\
`
`EEEEEWQEEEEEEEEEEEEEEEE\EEEEEEEEEEEEEE:
`
`EEEEEEBNEEEEwEEEEEE:®EE%h%hEEE%CEEEEEE%\
`
`EEEEEECE:®EEEEEE)EEEEO
`[001m
`
`EEEGEEEEEEEEwTE\EEEEEKEVEEEEEoTEEEETwEO
`
`EEEE\EEEEmEEEEEEEhEEE®EEE(EEEy)E EEEE E4
`
`EVEEEKEEEEEEEKEUTEEL “EEEEEEE®wEEEEEE§h%
`oEEEW®EEEEEEEEEEEEE5EEEE\EEEEEEE EEE‘EEEC E
`
`40
`
`EEEEEBE:EEEAEEELEEVEEE‘E:EEEWEEEEE%GEE E
`
`EEWmEEEEEEéhEEEEEEEEEE EXEVEEEEEEEEEEEEE
`
`EEEEELTEEEEEWEELEE EEEEBE: EEEA£EELE<< EE E
`
`EEWEWEEEEO
`m020]
`
`EEEE WEmEEE<EmE)EEE€EE EEGEEEEEEEEETEEEE
`
`TfibxfiflwflfiifiEthTMEEAkfl\fikmfiflfifififimkEEEwa
`
`(EEwOEEEEEE\WEQEEEEEEEEEkbaEEEEEEEEEEEET
`
`EU\EE®EEEEEEEHBHTWEEEEE\EEEEWEEWEbEEEEhT
`
`wffiimoE:EEEE‘WE®EEEEEEEE§Eme:EEEEEEEE$h
`
`50
`
`

`

`($0 fifimfi: fifiifi“fi5hfm%%fiEfiT$:fl@flfififi§wtfifiéh
`
`(6)
`
`JP 20127183031 A 2012.9.27
`
`TLVC%$bm
`
`Mozll
`
`TwfifiTfimfibgfi$$<fifimbfiflhéafimT% fifiiflfiUfi: fifii
`
`WmmfifimuT @4TVEflfimmfififififififiéflfiT %h%h%$$<W%éh
`6 k4fiV§mfimwfifififififia%%afl fiib<flfififi§fififimtfiwfi
`
`wfiaTfififiafimfimmmwfififitTfiéo
`
`m022]
`
`@wu—X%N4ivzmfimmfififim%fifi&bffim5h%fi%fiaLTHTm
`
`fiTUVflfiEfi&%otwu—z%flKTVX®%mmfifi®EmfifiwaLTEfié
`
`flTfifim%®Efltfiéififi%fluuTM%T$flfi5fi£énChg mflfiiwa
`
`fiflfifl?§:tfiflfifi%%fiTfimam@®fiafibfiT£%VMUV%EM@
`®fi&fib€fi%ibma
`
`mozs]
`
`fiWEMT1®EKTVIflfimioffi &G%:EW§®2§KfifléhTmT%
`
`$< 20®EftV§flfiE$DT¥T~¥:é fifi$®3$m%%énTwT£$<T
`
`Eamfifi®m4iVfifififiiof4EMLKAflEfitfifiéhTmT£gwofifi
`
`EwfifififlTfithmfiafiu; UTEEEfimT%T&fiT%éT
`
`m0241
`
`%:®%ffi fig EM‘WEWEE®@EWK%4iV§fifiTETé: afifiibw
`
`[002M
`
`E: fifi§®%@m&wfi EwmmmtmfiuT $XiyfimfimgoTfifiénTw
`
`ékTWEEW®fimfl¢EEEEhTWéCaZ+&3Mg2+®$5fi$4$VflT
`ME§#B%:%%§at%QLT%:%fi§WTfifiéh%ofioTT%:%fi§mT
`
`memthTm%En%o
`
`moze]
`
`% fiafi: mfifififiéfiwkwT wfifiafififiamT §&1§Tfi9f£$<
`
`TiakmfimHBmeT%gwo
`m027]
`
`fifiMThflmfi fiib<mnhdmmmfifi§tfim§tfifi‘ HE-n% fifiim
`
`®%#%%§&§%#%mifinfiTbéoflfiEHTfififitnfitbotg;m T
`
`ME§%%%$$DI§VflELTT@ERH%EEE@%fifi%flEEELTQ$DO
`
`fifiwfifimflfiiafimiaTEHéfifiaThfiT$0fi$fiflflfiflflTfi5ca
`
`h*6%50
`[%%®fl%]
`
`mozsl
`
`$%mm;mfiT%mfi¢afifiéhTmafifiE®@%fi%bT@flTééthm
`
`mfimfimfiamaLTfimLkmaEm@$mwTa%MaTfiqummfiflfim&
`
`E%&LT%MLE@&EflW¢%CtfiT%6°ficTTfimfiflmti%twn—Z
`
`%N%fi?2®flmmfifi®flfijxEEfifibfién
`
`[Efi®%$%fiwl
`mozgl
`
`[Ellifiwflfifififi%fiflfi%fiflfl%$?o
`
`[EZ]$flflfififi&%fi§W®UVEfiGMEGEEEk®357EfifO
`
`[m3]%flflm3w%m-%m§m®uVfikwmmwfifiimwfia7TfiTo
`
`[E4]iflflwxfi%%:%fi§W®Uyfi&UM%®%§§m®V57%fific
`
`[E5]fiflfl?fifibk%fififi£fi®fl%%flfi%fi?o
`
`[E6]REWEEH%%E$W®UVEKGMfi®§E§m®557EfiTO
`
`[H7]ifimmfiw%%%§W®UVEfifiMfl®fiE§k®fifi7TfiTo
`
`10
`
`20
`
`30
`
`40
`
`50
`
`

`

`(7)
`
`JP 2012*183031 A 2012.9.27
`
`[EEEEEEEEEQEE]
`
`[003m
`
`EEEGEE®EEE9m1\EEHEEEELEEEEEEEDEEEE\meE
`
`EEMIEEEELELM
`
`m0311
`1 Ex EEHHUDEEEEEEQEEEEIEEEO EII'E‘LE EEEU‘UVE’E‘ED
`
`\EEEEEE®EEKowTEEéhTwaG
`
`woszl
`
`@lfifiéhéEEEWEEIE EEI4MUBEEISNAEWOT\%EEZa
`tEE EEEaatE: EEE4atflEt—“UBMTEO E:EEE4a®EEEE
`
`10
`
`LELHFEEEthEE EEE3baE: EEEZLbafJ‘JIIEPCE‘x66 h'CIn/E EE EEE
`
`3aaE4EEE4atE fiffiyxfifiITaKEOCE$éhfwé EE EEE
`
`3bbE:EEE4b&E [SE/{EVEEEl7bicckc'CflEEE‘éh'sza EEEE’E
`
`EIE‘Hi3flbeflfifi%\fi&®WE§tEE EEEaE:EEEtEEEEU
`Ehftnfracktno
`
`moss]
`
`[Sfi/r'zrVfiEE17aJEU‘17bE IEJE @FEKEVEEHETE21%$< EEEEE
`
`{EVQJEE'GEUTEEI/‘c [E/fzi‘VijEEODBflJf/i‘ 7X]‘L?i§?~7f‘b79AMXR
`
`EAGCIV V“:7'JV fififié'lZI/E 7J‘V AMV’G‘ZB'évb’k CNBFCBEE'EWZEL‘O
`
`[003M
`HEEEzbUDBEEEHcEE:EEE4aODIEE1EIJE [E4’2I‘ViiEE16blana’CBEE
`
`EhwaDEEEZaoEEEEE: EEE4b®EEEEE fifiVfiEElaa
`
`EUlecfiEwghmeOI11E\EEE‘EE EEEEUE:EEEE2Efo
`
`:EEE 3EMLEOTEEEEKOVT£ EEKEEEE(EEEECEV)EE
`
`EEEt EEKfiEEE<EEEEkfiD)E: EEEQEEEEE EXEVE
`
`EElsfiEHBhé E4tVEEE®EE\ 7XFAEEEEE790MXREAG
`
`CIVV“:“J"UV EEEEIVE PJ‘V CMVUEEUX :hEicBflEz’ShEmo
`[003m
`
`EEEzaEUzbE EEEWEUWEE5EEoTEEéhTwE EEEEES
`
`aEUSbE EE MfiflfififikioffifiihTWE E: EEE4aEU4bE
`
`E:EEEEE7M;91EEEnTw%
`
`mosel
`
`Ewu—XEH4EVXE\EEEHEE\UVEREEmeatEEEEMLTX
`
`VUEfifibéhéo%®fixm%RUWEéh\EWDEZREAEtWUEZfiflm
`
`maEém fikfififi5fl%omfifiwfi‘Cfibffiahk%kfifi\fifififiifi
`EEEEEEE’MEEEEEEhEG flEflzEbi‘ HEE<ELTC 5EEEEEEE‘EEWE’G
`
`EOTE;<\EEaLTCBEEEKEEEEEEEUEeTEEwDEEEEEEE
`
`EEE EEEEVV(EEEE)EEEEC2a,2b)EEmEEEEE5EEEE
`
`EEEEEV Vamtfiné EEEEE E1KEofEmEEEEtéE\EEEE\
`
`EEE<2a,2b)tEmEEEEE5aEEEEEO
`m037]
`
`EEEEES,SthEEEEEEsmE\EJEVEEEEEhéoEKEVEE
`\EE EEE<3a,3b)EEE EEEEEGEEEEEEEVblomaEh\Ch
`
`EOE%fi%é€%h% E: EEE4 4b8%:@HWE%7Efi\%4iymfifi
`E32160 REE/{EV 7k®fififfibi\ EE EEWEEGGEEtEE'GEEO
`
`Moss]
`
`EEEEEEEIEEEEET EE14EUEE15EKEEd5a\EEE2a,2
`bWfiEmEEEaEEhmeEEEUUVEEEE EEEsa.3b«aEEE%O
`
`6:035:35 [SE/rzl'ViJEJE17a,17bt®¥flf~flfiffichwUVE(EEAEUUVE
`
`{fiViPO43’®fifi)®gEfiEu\EKEVfififilTa,17bk®fifififi
`
`20
`
`30
`
`40
`
`50
`
`

`

`(8)
`
`JP 20127183031 A 2012.9.27
`
`meM%(fiahEfiMflfi¥:CH3COOHwfifi)mfiflfifigbgfiwo
`[003m
`
`UVEKfiVfi\@%#V§fifi18a,18b&fifibf\égfifi:fifi§4m
`
`4bmfififl?%kbx%#%%§3a.3bW®UVfi§EH\#EEWLk%E%&
`Efi9b%@\%:%%$4a,4bW®UVfifiEWEML%béofibDE\fiég
`
`fiESa.3bW®ME%EWEML%b50
`
`{004m
`
`#fi\WEEZbW®%Wfi$EfiEEhTm&CaZ+R§Mg2+®$5fi%¥fi
`Vfi\@4fiyfififil6b?fifibf%:%m%4amtgfl?éofifiEZaEEW
`
`(fixfikfififififihfi$4iyflfiféhfihfiuflfifikfifimfi%5hioffi
`
`mfifimfi$2bfitfifiéfléfib\fifiithfiwT%¥fiyfififiEhénE1
`
`mgfiémfmfimmfiifififlfi%%fimfl‘%®;5fi%fi§mfimt%4£vfifi
`fiéhéo
`
`m041]
`
`#Efifix$fififi£§éfifibkfi\MEfimfififlfifi5W%fififiéfikfibB
`
`M\UV%\MM&6@%tVfiWfiEh%O%LT\¥#%EWfi%SW®K%WEfi
`
`m&fiflfiém\fi:fl@flfifi7fl®$fifiuwuyflfi(Uym41y&fi%4iy
`
`)fi\%fl%hW$Ehéo
`
`[004m
`
`mfiéhfifimfi(mfifikfi9)@‘WfifimfiEW%%stfifiéhfméfififi
`mfififlfiyfismaflfléhfiomfi%mfi9fl\I?/~W%filfimtm%éhé
`0
`
`10
`
`20
`
`MO43]
`
`$éfiflflfifi6WEfifii%m%mfififl\fiéflWMW%%6E%fiéhfwéfi
`
`#@EW37010KtEW$fi%O$ZEEWE$TW%%$€§UV%EK@W§~
`
`fiiflfififlfifi7mfifiéflfw§%:flfiflayfi12maEWEhéoC®$5E
`
`\$%%?@\$fififi%%l%mwfxfikfi$fi§fiéhéfifikfiUVfi%+fim
`
`@fibxfioxfifimmfiéaafimfif@éo
`
`[004M
`EMEmtuymfimmfilam\twu—X%A#tvxmfimmfifltfiflméh
`
`30
`
`%0-fi\EWEhkfiflmfifil1@\fifiéhf%$<\m®7ntxwfiflabf
`
`ififlfiéfvtfiibu
`
`[004M
`
`[fifiW]
`
`fiftifiofirfifig)
`(1.
`k»m~x%w%17xabf\fi$%%fi®fififififlb\fi$flfifiUVfl%fim
`
`L\2§U—%%flbkccozéu—M‘WE®%#Tmfiéh\twu—x%n(fi
`
`vxfl%mmfi%éhto
`
`m046]
`
`(2.fimfi®%fififi)
`
`flmmfiflfi®fimfi&\E1Kfiéhéfififi$bk§fififi£§(§fifl)&%m
`
`(\Wfiflfibkufifiifififi%fifi\mfi§(fifimWD\$#%%§(§EWML
`
`)RG%:%%§(§EMWH)E\%h?fi1®fiifhéo
`
`[004H
`
`fixfiyfififiabftustVCMv(AGCIy9:7UVVfifi%HJ\@%j
`
`yfififiabftpatyAMv(AGCIyV:TUV§Hfi%fi)fimwantom
`
`fifikfififlfifi\fiéfififlfififiwfi:flfiflfifimfifim§u\%h%h1LaL
`
`\fififlfl/fitbkoWWEdewvtbtofififififififi‘fifi%@®%fiTfi
`
`Efiiéhfco
`
`m048]
`
`40
`
`50
`
`

`

`(9)
`
`JP 20127183031 A 2012.9.27
`
`mfifimfiEW%%\%#MEW%%&G%:mEW%%W®UV%%E&UM%%E
`
`u\fi%bn7%fifi7¢—EmwTWEéhto
`
`[004M
`
`E2@\mgimwuyfi&6MM®%EEk®557%fiiofififl$fi®uyfifi
`
`GMflQfiEH\%h%hQMmmn&GummmmnfiéofiufiflfifiéUVfimfi
`Efi\EE?E%M@®%E$U%$<M9L\$fififi£§®fififi%%flfififi0ml
`
`flttoka#fi\%flfi%%M@fi\UV@%EWRMmMH&fi9E4fiE%#8%
`
`’1’lrifigi’3‘1LEFL‘
`
`lilfilfifi'i‘OHmI/LEF’EUTCQ
`
`[005M
`
`ESQ“%#%%§W®UVflfifififi®fi§§k®§§7%fifioEWWIIEHR
`
`omeHUVflmfifififiwEflkn@@T%%Uyfl®fiflmxfifififi%fiofifi
`
`%%E@#5%mfi%fi\fifi%%%4%%%b5mmwwfibko:nfi\mfiifia
`
`fi—fififiakfiflkayflxiyfi‘$5u%:%%§«kfiflbttbfifiéo—
`
`E\E@T%%MQ®fiEM\Uyflfifififi9b%b%flfififiififlommflfi$0\
`%®%@%&m%mb%wko
`
`[005M
`
`E4m\%:%%$W®UVERUMflQE§§m®§57%fi?O@Wfilsuflu
`
`0%mmnuyfimfimfifiwghtofififi$§uyfimfigm‘éfififigfi®fifi
`
`fi%fi%flgfimbfiflkoéfi\M@%§fix§fi%%%Mfififiifi0mflflfifio
`
`to
`
`[005m
`
`C®$5E\fiflmfifl\fifififififi®§fifi%fil4fiflfifibkfififi\fi#%
`
`fiim(%gfifimfifim)mam&wafimfién‘%:%%§W(%:@EW%%W
`
`)KHUVMQ$§%$MQ%LTMWEHEO
`
`[005M
`
`[mfimu
`
`%%Mtfib%mfi%\H5Efiéhé¥fififi%fi21%fiwffifififibte%3
`
`Efififi%%H\fififififiJivfififim;orzfimfifléhrwfimaamm\%
`
`mWfimmkfifiEWEEtfififiE%ofifififi%fim\imflafibabko
`[005M
`
`5 Mixfihzafifiififififiz I‘NL Hflifiia 3 aEiZFz 3 bWODfiftWFMCEfiE
`
`h%UV&&6Mfl@\@Kiyfi&fi32&fifibffifi§22bkfizzcmafifi
`
`¢%o
`
`[005m
`
`10
`
`20
`
`30
`
`E6fi\WEEWQUVfiflfifl$®fi§§k®fi§7§fifofifififigfi®fififi
`afif§GB%FEfi'G\ UVfiEfiZfiE’fi@iJ§J§fli0mol/Lk7§tako ifi’fififltlfijfifiim U Vfiffiffiffic‘t
`
`Da<fi?bka
`
`[005m
`
`E7m\gfifiWDUym&GMM®%E£m0557EfifoUyfiwfiguxfifi
`fififififlfififi%%fl$fiififififififimbx%®%fi%%fififimbko#fi.fi
`
`40
`
`flifigc; Eififfiflfiffifififii'ébio mol/L'Ex ’E—mffifi’éfmmi‘abnb‘ %®?‘§Li%f§llcifi
`
`but/7h
`[O 0 5 7]
`
`E6gbxfimfi%+fitfififi%kbwmxEfififigfi%wgfiutfiki%%g
`N§éaL#L\E7Efi$hé$5fl\fififi%fiwfifiMLfifl\fifi§W®UVE
`
`fififififi§®§fi$é<fi%tw\UVMESME%%ELTEW¢%CEM$W%?
`
`35-3730
`
`[Efiiwflfiflfifi]
`
`[005m
`
`fifiwmflfiWEWfifixfifififlfifififl?fiflfiflt%tbmfifififigfid‘I
`
`50
`
`

`

`m
`
`m
`
`w
`
`$w#—fifiwfiwffimfi@%o
`
`[H%®%m]
`
`(10)
`
`JP 20127183031 A 2012.9.27
`
`m $
`
`fi$®¥fififi%§
`
`2btflfifi$
`3bzfiéfimi
`
`4b:%:%fi§
`
`5 9
`
`351393
`
`:mfifimfififlflfi
`
`ifiéflEW%%
`
`CEZflEWfifi
`:mmfimfigmay&
`
`Cfifiifififtifi
`Ififlflfiflfiyb
`
`Ifigflfiflfi
`I%:%EW§V§
`
`C%:MEW%
`
`16c
`
`17b,17c:@4ty§fifi
`18b,18c:@4fiyfiflfi
`
`IEEWTEfiLkflEWW®$fiEfi§E
`
`22b, 22c:?§fi§§
`
`1 23b, 23Ciflfifitfi§
`
`:Mfifimfifimfifi
`
`rmfimfifi
`
`IMEfimfifimayfi
`
`:Hfiififikfi
`
`:flmWaya
`
`:mmmfi
`
`32c.32d:@4fiy§&%
`
`.33c:$¥fiyfififi
`
`O w
`
`aH
`
`oom~c3©oc~qcnquuswwmqmgwymmmwowooqmm
`
`[0
`
`mmwwmmmmmmmmmv—HHHwHP-l—H
`
`

`

`(11)
`
`JP 20127183031 A 2012.9.27
`
`
`
`[El/1]
`
`[I5]
`
`
`
`

`

`(12)
`
`JP 20127183031 A 2012.9.27
`
`
`
`
`
`

`

`(13)
`
`JP 20127183031 A 2012.9.27
`
`7U? FN—VUDfiE’
`
`(72)3EHH% DEED
`
`fife
`
`fiJfiLfifififilEflfiJ I Imfiflfi 1 E 1 F?
`
`J I lfllfifiififikflfififlflfilfiaw
`
`PB12
`PAD-4
`JASBA MA03 MA13 MAI-4
`Fa—Lxcéjfi) 4D006 CA1? HA41
`4D061DA10 D1318 D1309 DC13 DC17 DClQ EAOQ E1301
`
`PB25
`E1313
`
`E1319
`
`

`

`Espacenet - Bibliographic data
`
`Page 1 of 2
`
`
`
`Eaeacenet
`
`htiesareiiiiiisiiiiiiiitiéiéiEtta3iiEtta???Iiiiitati3-525tiiii-3t}tiiii-It?iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiii
`
`aereoo eoe ececraonrawaia area AeeAaArua Foe eaacreoctAtvaia
`
`|nventor(s):
`
`MASAMOTO MANABU; IZUMI NORIAKI; KONISHI SATOSHI;
`IKEDA MICHIHARU j; (MASAMOTO MANABU,
`; IZUMI NORIAKI, ;
`KONISHI SATOSHI, ; IKEDA MICHIHARU, 1512K e, ; rue eat;
`4% Hit
`,
`; ittEH are
`
`Applicant(s):
`
`KAWASAKI HEAVY IND LTD : (KAWASAKI HEAVY IND LTD,
`mealeeitee)
`
`; )II
`
`C|assificatiom - international: earner/44; Baffler/’46; career/area; 6135(1/92
`- cooperative: Y02A20i134
`
`Application
`number:
`
`JP20110048456 20110307
`
`Giohai Dossier
`
`Priority number JP20110048456 20110307
`(5):
`
`Also published aeaeaseia gee.)
`as:
`
`Abetract of JP2012183€331 tie}
`
`PRQBLEM TO BE SQLVED: To provide a method tor eiectrodiaiveia in order to
`tractionate and recover a ciuraiity oi kinds of acids from acideaccharitied iiquid, and an
`apparatus tor the eiectrodiaiyeia, used for such the method for the
`eiectrooiaivaia.SOLUTiON: By using the apparatus for the eiectrodiaiyeie, the oiuraiity
`of kinda of the acids are fractionated and recovered from the acid—saccharitied iiquid of
`ceiiniose~haeed hiornaes, At the apparatus for the eiectrodiaiysia a deeaiination
`chamber and a concentration chamber are inetaiied, and the concentration charriher ia
`divided into a first concentration chamber at a cathode side and a second concentration
`
`chamber in an anode side by an anion exchange membrane. At the deeaiination
`chamber, a deaaiinated saccharitied iiquid recovery pathway is: connected, and at the
`first concentration chamber, a first acid recovery pathway for recovering the acid having
`a tow permeation rate toward the anion exchanging membrane among the acids
`contained in the saccharitied iiauid in the deaaiination charnher is connected, and at the
`second concentration chamber, a second acid recovery pathway for recovering the acid
`having a high permeation rate toward the anion exchanging mernhrane is; connected.
`
`https://wor1dwide.espacenet. com/publicationDetails/biblio?II=O&ND=3&adj acent=true&loc. .. 2/8/2019
`
`

`

`Espacenet - Bibliographic data
`
`Page 2 of 2
`
`https://wor1dwide.espacenet. com/publicationDetails/biblio?II=O&ND=3&adj acent=true&loc. .. 2/8/2019
`
`

`

`2012183031-Desc-en
`
`Page 1 of 9
`
`Powered by EPI) 322:1 (Boogie
`
`Patent 123333131e
`
`T1215: 22321523220212 machinege2‘2e'2312321:tc3nn0I e r22I23n1eed tt‘a' it:s 221123129230 accurate complete 222231210 or-22212 2
`such as I.“ 31322221201321}; relevant or nuanciai decisions, shouid 2201 be based on Ina-.212Ede—223213132202": 2122222221.
`
`23:32"23221:: purposes. (321220231 decisions,
`
`
`
`I2123I21I2s 22':22I2 I221
`(:2352621311221C1 23222231 5:122:15;
`:22eI2'11223:1123132515 2:2:311222121 1:22' 5:223:223212Ig I22II2'
`PROBL 131211 TO 232?. SN..Vt—ED: 1:: provide I321
`acid g2yeated "quid end 321 e:eetredial‘,21ss so I-e3231225 us ed for r‘ar2y2ng 0221 5222311 an elest2c-di
`iysis method. I:SCILUT1C2N1 2n the
`I22'I:2sen1 222V::21tiI'-21, 231122222 2:112:35 2313I;i215 3223 s3I3II3II2, 322:1 reIo‘Iered 2'2'I22I2 3n soid g:'VII;I31ed-:'ioI22I1 I21 031i I22'o5iI 222022223555 by usi 21g
`322 electrodiaiyzer. The :22e231223I2'1231yzer is 21211122212321 2122112 23 21352311122123 2:22I22Iii>:22' and 3 23021233211223'122123 232132122332 and 11223 (2232223232212'I21ing
`chamber is d1212dec1 inte- e 1125-: concentrating chamber on the cathode side and :2 second ceneenhating ehan1be2‘ I222 the anode
`52:15 by I221 322:'on ::/:23hI3n:123 22'.- 2322113232223 ‘1':1:: de5I'2112n:2 1211222111232 15 CI-2‘:2'.-23I123d with :3 des3itedI2I2‘22I3221Id::2=:12d recovery 2322111,
`and 22112123 11251 2::2-:2I:::2I'1 2'23'22'2:1g:22322I'::-232.
`2322
`I2232221 12:3V2I2:; 3 2:22:12 23:22'222233222322223223 1221121 2:25;)3:2231 1:2 222:: anion exchange 2Iie22213223r2e
`among the acids contained in the saccharitied 53122222321
`in the deseit'i221g oompadmeht And a second acid recover}:2 path for
`223I:II2=ve22n:2 I322 acid having :2 his; 12 permeation rate to the anion 3XI;212221ge 222:2:“1113161128I15 CI~222223Ited tI21the 5e23232221 concentration
`23213232223321 (F18.
`
`Eieetredialysis method and electrsdieiysis appara1us
`
`{33313
`
`TECHMCAL HELD The present invention 2232:2tes to a method 12.22 5eI2I2rI2t2nI; I'2nd reeovedng 3 23iI2i'a222y I211<22221s 2313I2I15 120211 322
`
`
`ae1I13I30htai
`g 11I2=.22I2 such I35 an acid seocharit’ioeiion treatment 1123;221d which is a product obtaihed by saccharifying ce11uiesic
`biomass using 321 acid by e1eeti'edia2ysis, 321233" method To 321 e1eeti'edia2ysis appa23tu5 used to: 322 e=e231'dd232ys2s method for
`IeIzovew.
`
`{33322
`
`there is an attempt 223 31323121 ethano1 (bieethenoi) by deeomposéhg ceiiu2dse or
`As 3 2.23:: of biomass energy u122izetion,
`11::2112I;:3222.22I25:2. whioh is a main o23II1pI2he2Ito123ia21t5.
`
`12 is planned 12123'1tztie2I:-i23122eI2'::th221:21 is 22322152 h22xedi2'1he 23:21:222I:21>:'::2 122231 2I2I21211y for 12292 232 used as an 31191222312222: 12292 2232
`gesofine.
`
`{22212232
`
`1:5 23222232359 obiained 12y deoornposing
`2311122322222
`21223221 are 2332222205223, 222322212323111212359, herein 23: 512322312.
`The main (22322233213225 31211::
`cellulose. xy1ose obtaihed by decomposing hen12oe22uEI2se, seeoharides such as oligesacehemies which are commexes thereof
`A5 :3 23w 21133322222,
`it is produced by 121:: 1232'22223I21312on action 2312niI2'oor:23221sn2s 5:22:22 35 3223332.
`
`233343
`
`122 order 1:) decompose sellulosic biomass such as eel1221ose er hen12oe22uEI2se into saer‘1Is21Iie23,s a method (acid hydrolysis
`method) I2122ydr231yzi21g 132; I322 oxidizing power ofan 3:2:1 5= 2‘22 :35 phos I:- 21022:: I323:'d 232 512.1122212‘ I223221'is 2323222323213: used.
`
`http://translationporta1.epo.org/emtp/translate/?ACTION=description-retrieva1&COUNTRY. .
`
`. 2/8/20 1 9
`
`

`

`2012183031-Desc-en
`
`Page 2 of 9
`
`is preterabie to
`it
`in this acid hydroiysis method, since the added acid serves as an inhibitor against fermentation ct" yeast,
`
`decompose ceiiuicse or heniicelluicse into sacci .irides and then add the acid to ethanol
`,c-rior to ethnic-i fermentation of
`saccharides contained in the saccharit‘ied sciution Must be removed or neutraiized.
`
`{ones}
`
`Patent Document 1 discioses a technique of removing suituric acid in a saccharified solution by adding hydrated time to an acid
`saccharit’ied solution to neutraiize suituric acid and soiid~iiguid separating the formed gypsum. Here, it a strong acid added from
`the saocharit’ied solution can be recovered, a base for neutralization becomes unnecessary and cost can he reduced, but in the
`
`method dis oised in Patent Document 1, suituric acid is regenerated front gypsum it is ditticuit to do.
`
`{coca}
`
`Cin the other hand, Patent Document 2 discioses a technique of tiowing an acid saocharit‘ied solution through an ion exchange
`resin to separate and recover suifuric acid. in addition, Patent Document 3 discloses an acid sacchariticaticn step of producing
`an acid / sugar mixture by subjecting ceiiuiosio biomass to acid saccharification treatment and a step ct using an anion
`exchange membrane for an acid i’ sugar mixture obtained from the acid saccharii‘ication step And a diaiysis treatment step of
`subjecting the acid and the sugar sciution to a diaiysis treatment by a diffusion diaiysis method at a temperature of 53 ° C or
`tees to produce a sugar solution from ceiiuiosic biomass . The method disciosed in Patent Document :3 is aimed at rnaidng it
`possibie to reo ver and reuse acid by using an ion exchange membrane and to reduce the energy cost and environmentai
`burden of the whoie process.
`
`{cost}
`
`Patent Document 1: JP 20967300? A Patent Document 2: 5? 26-35401 on A Patent Document 2: .JFLA 200922180
`
`{coast
`
`in the saccharitied solution, an organic acid {weak acid) which is a byproduct of ceiiuiose or hemiceliuiose saccharitication
`reaction is aiso contained.
`
`Since the inorganic acid added in the sacchariticaticn step is high in concentration and expensive, it is preferable to recover the
`
`
`inorganic acid from the saccharitied soiution and recycie it. i-iowever.
`.e the inorganic acid and the organic acid coexi
`(i the
`saccharit’ied soiution, when the inorganic acid mixed with the organic acid is
`reused in the sacchariticatic-n step,
`the
`concentration of the organic acid in the saccharitication stoc- increases. which adverseiy affects the saccharit‘ication step in
`addition to this, it aiso causes a rise in acid recovery cost, and furthermore. there is a probiem that the organic acid which can
`not he recovered hinders termentation in the subsequent termentation process.
`
`goons}
`
`On the other hand, with the methods disciosed in Patent Documents 2 and 3,
`piuraiity ct Kinds of acids contained in a saccharit‘ied soiutic-n.
`
`it
`
`is not possioie to separate and recover a
`
`{onto}
`
`
`
`
`ELD The present invention reiaies to an eiectrodiaiysis method t'cr separating and recovering saccharides and a
`TECi-iNECAL
`piuraiity oi kinds of acids from an acid saccharitied solution which is a product obtained by saccharifying ce" osic biomass with
`
`
`an inorganic acid and a ntethcd for using such an electrod" iysis method And an object ofthe present invention is to provide an
`eiectrcdialyzer which is to be charged.
`
`{cost}
`
`The present inventors diiigently studied a method for separately recovering plurai kinds of acids from an acid-containing iiduid
`such as an acid saccharitied soiuticn.
`
`the
`in the eiectrodiaiyzer provided with the desaiting compartment and the concentrating compartment.
`As a resuit,
`concentrating compartment is divided by the anion exchange membrane, and the concentrating compartment is separated into
`
`http://translationporta1.epo.org/emtp/translate/?ACTION=description-retrieva1&COUNTRY. .
`
`. 2/8/2O 1 9
`
`

`

`2012183031-Desc-en
`
`Page 3 of 9
`
`the desaiting compartment and the divided concentrating compartment by independent recovery routes ') To desaiinate the
`
`saccharified solution, it is pc-ss ,.e to coiieet and recover pibral kinds of acids having different permeation rates with respect to
`the anion exchange membrane therebv compieting the present invention.
`
`roots}
`
`
`
`ent invention is a method of separating and recovering a piorality of kinds of acids from an acid-containing
`Specificaiiy, the or
`iidnid by eiec rodiaiysis. wherein the plnrai kinds of acids are different from each other in terms of a first acid And a second acid!
`wherein the rate of permeation of the first acid to the anion exchange membrane is tower than the rate of permeation of the
`second acid to the anion exchange membrane, sc- that the acid Passing the second acid from the cathode side to the anode
`side of the first anion exchange membrane, a second permeation step of passing the second acid from the cathode side to the
`anode side of the first anion exchange membrane, Through the second anion exchange membrane from the cathode side to the
`
`anode side and permeates ihe first acid contained in ihe acid saccharificaiiori soiuticn from the cathode side of ihe iris anion
`exchange membrane to the anode side And a second transmission step
`
`{oars}
`
`it is preferable that the first acid is an organic acid and the second acid is an inorganic acid.
`
`{core}
`
`it is preferable that the acid~ccntaining iignid is an acid saccharified liquid of ce
`
` m
`
`roots}
`
`The method of the present invention preferably has a recovery step of recovering the acid. saccharit’ied solution from which the
`first acid, the second acid, and the first acid and the second acid have been removed.
`
`{cars}
`
`it is preferable that the recovered second acid is reused in the acid saccharification step of ceildlcsic biomass
`
`{port}
`
`invention aiso provides an eiectrodialyser for separating and recovering plurai kinds of acids having different
`The present
`perrneaiicn rates ic sugar and anion exchange membrane contained in an acid saccharificaticn fr .atment soicticn of ceiiiiiosic
`biomass, wherein the electrodiaiyzer is provided with a desaiting chamber and a concentrating chamber, and a desalted
`saccharified iiduid recovery path is connected to the desalting compartment, and the concentrating compartment is connected to
`a desaitrng chamber at
`the cathode side having the anion exchange membrane between them A first concentrating
`compartment and a second concentrating compartment on the anode side, wherein the first concentrating compartment is
`provided with a first concentrating compartment for cc-iiecting the first acid having a tower permeation rate to the anion exchange
`membrane than the second acid A second acid recovery path for recovering the second acid having a higher permeation rate to
`the anion exchange membrane than the first acid is connected to the second concentration chamber, An eiectrodialyzer (first
`eiectrodialysis Device),
`
`{core}
`
`invention aiso provides an eiectrodialyzer for separating and recovering plLirai kinds of acids having different
`The present
`permeation rates with respect to sugar and anion exchange membrane contained in an acid sacch'iriticatien treatment solution
`of ceiiuiosic biomass, Wherein the acid comprises a first acid and a second acid having different permeation rates with respect
`to the anion exchange membrane, the eiectrodiaiyzer comprises a desalting compartment and a concentrating compartment, An
`
`ion exchange membrane ., id corinecied w'th a desaited saccharified soirition recovery path, wherein the concentration chamber
`has a cation exchange membrane on the anode side and an anion exchange membrane on the cathode side. respectiveiyr A
`first concentrating chamber on the cathode side having an ion exchange membrane between each other and a second
`concentrating compartment on the anode side, wherein the first concentrating compartment is provided with a permeation
`membrane which permeates the anion exchange membrane The first acid recovery path for recovering the first acid having a
`
`http://translationporta1.epo.org/emtp/translate/?ACTION=description-retrieva1&COUNTRY. .
`
`. 2/8/20 1 9
`
`

`

`2012183031-Desc-en
`
`Page 4 of 9
`
`tower rate is in contact A second acid recovery path tor recovering the second acid having a higher permeation rate to the anion
`
`
`exchange membrane than the first acid is connected to the second concentration chamber
`:altino the acidic saccharltied
`solution in the desaiting chamber and cciieoting the first acid and the second acid from the first acid recovery path and the
`second acid recovery path, respectiveiy , And an eiectrodiaiyzer (second eiectrodiaiyzer).
`
`roots}
`
`in the eiecirodiaiysis apparatns of the present invention. the concentration chamber is divided by an anion e